Water-based synthesis of zeolitic imidazolate framework-8 with high morphology level at room temperature
文献类型：期刊论文
| 作者 | Jian, Meipeng; Liu, Bao; Liu, Ruiping; Qu, Jiuhui; Wang, Huanting; Zhang, Xiwang |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:60页码:48433-48441 |
| 英文摘要 | In this study, the synthesis of zeolitic imidazole framework (ZIF-8) in water was systematically studied using 6 zinc sources (Zn(OAc)(2), ZnSO4, Zn(NO3)(2), ZnCl2, ZnBr2, ZnI2), respectively, under different conditions at room temperature without using any additives. It was found that Zn(OAc)(2) is the best precursor and the resultant ZIF-8 particles have the best quality with rhombic dodecahedron morphology. The concentration of 2-methylimidazole (Hmim), molar ratio Hmim/Zn and water content all have significant impacts on the morphology, particle size, and crystallinity of ZIF-8. Further result analysis reveals that 3 key reactions are involved in the ZIF-8 formation which needs five steps in ZIF-8 structural evolution. This study provides a deep understanding of the crystallization process of ZIF-8 particles in a waterbased system. |
| 研究领域[WOS] | Chemistry, Multidisciplinary |
| WOS记录号 | WOS:000355738300034 |
| 公开日期 | 2016-03-15 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/32698]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Jian, Meipeng,Liu, Bao,Liu, Ruiping,et al. Water-based synthesis of zeolitic imidazolate framework-8 with high morphology level at room temperature[J]. RSC ADVANCES,2015,5(60):48433-48441. |
| APA | Jian, Meipeng,Liu, Bao,Liu, Ruiping,Qu, Jiuhui,Wang, Huanting,&Zhang, Xiwang.(2015).Water-based synthesis of zeolitic imidazolate framework-8 with high morphology level at room temperature.RSC ADVANCES,5(60),48433-48441. |
| MLA | Jian, Meipeng,et al."Water-based synthesis of zeolitic imidazolate framework-8 with high morphology level at room temperature".RSC ADVANCES 5.60(2015):48433-48441. |
入库方式： OAI收割
来源：生态环境研究中心
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