High performance Pd catalysts supported on bimodal mesopore silica for the catalytic oxidation of toluene
文献类型：期刊论文
| 作者 | Qiao, Nanli; Li, Yang; Li, Na; Zhang, Xin ; Cheng, Jie; Hao, Zhengping
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| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2015-10 |
| 卷号 | 36期号:10页码:1686-1693 |
| 关键词 | Bimodal mesoporous silica Pore structure Catalytic oxidation Toluene Palladium |
| 英文摘要 | A series of bimodal mesoporous silica (BMS-x)-supported Pd catalysts were successfully prepared by a facile sol-gel approach, followed by an impregnation method. The synthesized catalysts were characterized by several analytical techniques and the oxidation of toluene was used to evaluate their catalytic performance. Textural analysis showed that all samples had high surface areas (similar to 1000 m(2)/g), large pore volumes (similar to 1.2 cm(3)/g) and uniform mesopore size (similar to 2.6 nm). Defining the level of ammonia solution to within a certain range resulted in the catalysts possessing a typical bimodal mesoporous structure with an intraparticle framework mesopore and an interparticle textural mesopore (18-40 nm). Transmission electron microscopy observations and CO chemisorption results revealed that this unique bimodal mesoporous structure helped to decrease the particle size of Pd nanoparticles and could further enhance their dispersion. Activity tests revealed the Pd/BMS-5-Pd/BMS-20 catalysts with a bimodal mesopore structure possessed superior catalytic performance for the oxidation of toluene compared to Pd/BMS-30 with a unimodal mesopore structure. More importantly, compared with the Pd/MCM-41 and Pd/MCM-48 catalysts, Pd/BMS-15 had improved hydrothermal stability and catalytic performance at a high gas hourly space velocity of 70000 h(-1). These results indicate the potential application of the catalysts for the elimination of volatile organic compounds. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| 研究领域[WOS] | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| WOS记录号 | WOS:000362863700006 |
| 公开日期 | 2016-03-15 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/32709]  |
| 专题 | 生态环境研究中心_环境纳米材料实验室 |
| 推荐引用方式 GB/T 7714 | Qiao, Nanli,Li, Yang,Li, Na,et al. High performance Pd catalysts supported on bimodal mesopore silica for the catalytic oxidation of toluene[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(10):1686-1693. |
| APA | Qiao, Nanli,Li, Yang,Li, Na,Zhang, Xin,Cheng, Jie,&Hao, Zhengping.(2015).High performance Pd catalysts supported on bimodal mesopore silica for the catalytic oxidation of toluene.CHINESE JOURNAL OF CATALYSIS,36(10),1686-1693. |
| MLA | Qiao, Nanli,et al."High performance Pd catalysts supported on bimodal mesopore silica for the catalytic oxidation of toluene".CHINESE JOURNAL OF CATALYSIS 36.10(2015):1686-1693. |
入库方式： OAI收割
来源：生态环境研究中心
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