Enhanced Fenton-like degradation of refractory organic compounds by surface complex formation of LaFeO3 and H2O2
文献类型：期刊论文
| 作者 | Nie, Yulun; Zhang, Lili ; Li, Yu-You; Hu, Chun
|
| 刊名 | JOURNAL OF HAZARDOUS MATERIALS
 |
| 出版日期 | 2015-08-30 |
| 卷号 | 294页码:195-200 |
| 关键词 | LaFeO3 Heterogeneous Fenton reaction Refractory organic compounds Mechanism |
| 英文摘要 | Nanoscale LaFeO3 was prepared via sol-gel method and characterized by XRD, FTIR and N-2 adsorption/desorption experiment. The results indicated that, LaFeO3 had a typical perovskite structure with a BET area of 8.5 m(2)/g. LaFeO3 exhibited excellent Fenton activity and stability for the degradation of pharmaceuticals and herbicides in water, as demonstrated with sulfamethoxazole, phenazone, phenytoin, acyclovir and 2,4-dichlorophenoxyacetic acid, 2-chlorophenol. Among them, sulfamethoxazole (SMX) could be completely removed in LaFeO3-H2O2 system after reaction for 120 mm at neutral pH. Based on the ATR-FTIR analysis, the surface complex of LaFeO3 and H2O2 was formed, which was important and essential for the enhanced Fenton reaction by accelerating the cycle of Fe3+/Fe2+. Hence, more (OH)-O-center dot and O2(center dot-)/HO2 center dot- were then produced in LaFeO3-H2O2 system, resulting in more efficient removal of refractory organic compounds. Based on the surface interaction of LaFeO3 and H2O2, a heterogeneous Fenton reaction mechanism was proposed. (C) 2015 Elsevier B.V. All rights reserved. |
| 研究领域[WOS] | Engineering, Environmental ; Engineering, Civil ; Environmental Sciences |
| WOS记录号 | WOS:000355028700023 |
| 公开日期 | 2016-03-15 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/32771]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Nie, Yulun,Zhang, Lili,Li, Yu-You,et al. Enhanced Fenton-like degradation of refractory organic compounds by surface complex formation of LaFeO3 and H2O2[J]. JOURNAL OF HAZARDOUS MATERIALS,2015,294:195-200. |
| APA | Nie, Yulun,Zhang, Lili,Li, Yu-You,&Hu, Chun.(2015).Enhanced Fenton-like degradation of refractory organic compounds by surface complex formation of LaFeO3 and H2O2.JOURNAL OF HAZARDOUS MATERIALS,294,195-200. |
| MLA | Nie, Yulun,et al."Enhanced Fenton-like degradation of refractory organic compounds by surface complex formation of LaFeO3 and H2O2".JOURNAL OF HAZARDOUS MATERIALS 294(2015):195-200. |
入库方式： OAI收割
来源：生态环境研究中心
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