Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation
文献类型：期刊论文
| 作者 | Hu, XF ; Wang, XW; Dong, LL; Chang, F; Luo, YM
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| 刊名 | WATER SCIENCE AND TECHNOLOGY
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| 出版日期 | 2015 |
| 卷号 | 71期号:11页码:1679-1685 |
| 关键词 | aniline Ag-Cl complexes Cl/Ag ratio photochlorination |
| 产权排序 | [Hu, Xuefeng; Wang, Xiaowen; Dong, Liuliu; Luo, Yongming] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China; [Hu, Xuefeng; Wang, Xiaowen; Luo, Yongming] Univ Chinese Acad Sci, Beijing 100049, Peoples R China; [Chang, Fei] Univ Shanghai Sci & Technol, Sch Environm & Architecture, Shanghai 200093, Peoples R China; [Dong, Liuliu] Yantai Univ, Environm & Mat Engn, Yantai 264005, Shandong, Peoples R China |
| 通讯作者 | Hu, XF (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China. xfhu@yic.ac.cn |
| 英文摘要 | Ag speciation in a chloride medium was dependent upon the Cl/Ag ratio after releasing into surface water. In this study, the photoreaction of in situ formed Ag-Cl species and their effects on aniline photochlorination were systematically investigated. Our results suggested that formation of chloroaniline was strongly relevant to the Cl/Ag ratio and could be interpreted using the thermodynamically expected speciation of Ag in the presence of Cl-. AgCl was the main species responsible for the photochlorination of aniline. Both photoinduced hole and center dot OH drove the oxidation of Cl- to radical center dot Cl, which promoted the chlorination of aniline. Ag-0 formation was observed from the surface plasmon resonance absorption during AgCl photoreaction. This study revealed that Ag+ released into Cl--containing water may result in the formation of chlorinated intermediates of organic compounds under solar light irradiation. |
| 研究领域[WOS] | Engineering ; Environmental Sciences & Ecology ; Water Resources |
| 关键词[WOS] | AQUEOUS-SOLUTION ; RATE CONSTANTS ; SALINE WATER ; SILVER ; PHOTOCHLORINATION ; ACETONITRILE ; DEGRADATION ; MECHANISMS ; IONS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000355767100012 |
| 源URL | [http://ir.yic.ac.cn/handle/133337/9255]  |
| 专题 | 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 |
| 推荐引用方式 GB/T 7714 | Hu, XF,Wang, XW,Dong, LL,et al. Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation[J]. WATER SCIENCE AND TECHNOLOGY,2015,71(11):1679-1685. |
| APA | Hu, XF,Wang, XW,Dong, LL,Chang, F,&Luo, YM.(2015).Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation.WATER SCIENCE AND TECHNOLOGY,71(11),1679-1685. |
| MLA | Hu, XF,et al."Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation".WATER SCIENCE AND TECHNOLOGY 71.11(2015):1679-1685. |
入库方式： OAI收割
来源：烟台海岸带研究所
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