Formation of Ordered Coronene Clusters in Template Utilizing the Structural Transformation of Hexaphenylbenzene Derivative Networks on Graphite Surface
文献类型：期刊论文
| 作者 | Chang, Shaoqing1; Liu, Runcong2; Wang, Liancheng3; Li, Min2; Deng, Ke1; Zheng, Qjyu3; Zeng, Qingdao1 |
| 刊名 | ACS NANO
 |
| 出版日期 | 2016 |
| 卷号 | 10期号:1页码:342-348 |
| 关键词 | structural transformation HPB network coronene cluster scanning tunneling microscopy guest inclusion |
| 英文摘要 | In the present work, we report the fabrication of regular coronene (COR) clusters on surfaces in ambient conditions in the two-dimensional network formed by hexaphenylbenzene derivatives (HPB) via structural transformation. HPB could form a stable snowflake network structure on the highly oriented pyrolytic graphite surface at the air solid interface. When COR molecules were introduced into the system, the HPB snowflake network could transform to honeycomb structures, and the COR heptamers were subsequently aggregated and entrapped into the cavity. Scanning tunneling microscopic was employed to monitor the assembly behavior of both HPB and HPB/COR at a submolecule scale level, and density functional theory calculations were utilized to reveal that the structural transformation and the entrapment are the energetically favorable. The pores formed from HPB might also give a clue to immobilizing some functional molecule clusters, like COR, to fabricate their ordered monolayer in ambient conditions, so as to obtain complex supramolecular surface structures. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/30068]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Natl Ctr Nanosci & Technol NCNST, CAS Key Lab Standardizat & Measurement Nanotechno, CAS Ctr Excellence Nanosci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, CAS Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chang, Shaoqing,Liu, Runcong,Wang, Liancheng,et al. Formation of Ordered Coronene Clusters in Template Utilizing the Structural Transformation of Hexaphenylbenzene Derivative Networks on Graphite Surface[J]. ACS NANO,2016,10(1):342-348. |
| APA | Chang, Shaoqing.,Liu, Runcong.,Wang, Liancheng.,Li, Min.,Deng, Ke.,...&Zeng, Qingdao.(2016).Formation of Ordered Coronene Clusters in Template Utilizing the Structural Transformation of Hexaphenylbenzene Derivative Networks on Graphite Surface.ACS NANO,10(1),342-348. |
| MLA | Chang, Shaoqing,et al."Formation of Ordered Coronene Clusters in Template Utilizing the Structural Transformation of Hexaphenylbenzene Derivative Networks on Graphite Surface".ACS NANO 10.1(2016):342-348. |
入库方式： OAI收割
来源：化学研究所
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