Preparation of a series of aCTV-based covalent organic frameworks and substituent effects on their properties
文献类型:期刊论文
作者 | Zhen, Jingru1; Ding, Sanyuan2; Liu, Junmin3; Huang, Zhitang1; Wang, Wei2; Zheng, Qiyu1 |
刊名 | CRYSTENGCOMM
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出版日期 | 2016 |
卷号 | 18期号:6页码:1039-1045 |
英文摘要 | A series of amino substituted cyclotrianisylene (aCTV)-based covalent organic frameworks (COFs), aCTV-COF1 to aCTV-COF4, have been synthesized. These crystalline analogues showed permanent porosity with BET surface areas from 656 m(2) g(-1) to 1428 m(2) g(-1). With the introduction of methoxy groups and hydroxyl groups at the phenyl linker moieties in aCTV-COF3 and aCTV-COF4, their properties (such as color, gas adsorption, hydrolytic stability and so on) have been influenced to a great extent. The CO2 sorption of aCTV-COF4 has increased significantly, and the H-2 uptake of aCTV-COF3 is obviously higher than those of aCTV-COF1 and aCTV-COF2. Moreover, the introduction of the methoxy and hydroxyl groups has made aCTV-COF3 and aCTV-COF4 have better hydrolytic stability. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2016-05-03 |
源URL | [http://ir.iccas.ac.cn/handle/121111/30111] ![]() |
专题 | 化学研究所_分子识别与功能实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China 3.Sun Yat Sen Univ, Sch Chem & Chem Engn, KLGHEI Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Zhen, Jingru,Ding, Sanyuan,Liu, Junmin,et al. Preparation of a series of aCTV-based covalent organic frameworks and substituent effects on their properties[J]. CRYSTENGCOMM,2016,18(6):1039-1045. |
APA | Zhen, Jingru,Ding, Sanyuan,Liu, Junmin,Huang, Zhitang,Wang, Wei,&Zheng, Qiyu.(2016).Preparation of a series of aCTV-based covalent organic frameworks and substituent effects on their properties.CRYSTENGCOMM,18(6),1039-1045. |
MLA | Zhen, Jingru,et al."Preparation of a series of aCTV-based covalent organic frameworks and substituent effects on their properties".CRYSTENGCOMM 18.6(2016):1039-1045. |
入库方式: OAI收割
来源:化学研究所
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