C and N Hybrid Coordination Derived Co-C-N Complex as a Highly Efficient Electrocatalyst for Hydrogen Evolution Reaction
文献类型:期刊论文
| 作者 | Wang,Zhong-Li; Hao,Xian-Feng; Jiang,Zheng; Sun,Xue-Ping; Xu,Dan; Wang,Jun; Zhong,Hai-Xia; Meng,Fan-Lu; Zhang,Xin-Bo |
| 刊名 | journal of the american chemical society
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| 出版日期 | 2015 |
| 卷号 | 137期号:48页码:15070-15073 |
| 关键词 | OXYGEN REDUCTION REACTION REDUCED GRAPHENE OXIDE DOPED CARBON IN-SITU MOLYBDENUM CARBIDE TRANSITION-METAL COBALT NANOPARTICLES POROUS CARBON CATALYSTS NITROGEN |
| 通讯作者 | zhang,xb |
| 英文摘要 | development of an efficient hydrogen evolution reaction (her) catalyst composed of earth-abundant elements is scientifically and technologically important for the water splitting associated with the conversion and storage of renewable energy. herein we report a new class of co-c-n complex bonded carbon (only 0.22 at% co) for her with a self-supported and three-dimensional porous structure that shows an unexpected catalytic activity with low overpotential (212 mv at 100 ma cm(-2)) and long-term stability, better than that of most traditional-metal catalysts. experimental observations in combination with density functional theory calculations reveal that c and n hybrid coordination optimizes the charge distribution and enhances the electron transfer, which synergistically promotes the proton adsorption and reduction kinetics. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000366339900003 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/64536] ![]() |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang,Zhong-Li,Hao,Xian-Feng,Jiang,Zheng,et al. C and N Hybrid Coordination Derived Co-C-N Complex as a Highly Efficient Electrocatalyst for Hydrogen Evolution Reaction[J]. journal of the american chemical society,2015,137(48):15070-15073. |
| APA | Wang,Zhong-Li.,Hao,Xian-Feng.,Jiang,Zheng.,Sun,Xue-Ping.,Xu,Dan.,...&Zhang,Xin-Bo.(2015).C and N Hybrid Coordination Derived Co-C-N Complex as a Highly Efficient Electrocatalyst for Hydrogen Evolution Reaction.journal of the american chemical society,137(48),15070-15073. |
| MLA | Wang,Zhong-Li,et al."C and N Hybrid Coordination Derived Co-C-N Complex as a Highly Efficient Electrocatalyst for Hydrogen Evolution Reaction".journal of the american chemical society 137.48(2015):15070-15073. |
入库方式: OAI收割
来源:长春应用化学研究所
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