Preparation of Pd-Co-Based Nanocatalysts and Their Superior Applications in Formic Acid Decomposition and Methanol Oxidation
文献类型：期刊论文
| 作者 | Qin,Yu-ling; Liu,Ya-cheng; Liang,Fei; Wang,Li-min |
| 刊名 | chemsuschem
 |
| 出版日期 | 2015 |
| 卷号 | 8期号:2页码:260-263 |
| 关键词 | CATALYZED HYDROGEN GENERATION METAL-ORGANIC FRAMEWORK AMBIENT CONDITIONS ALLOY NANOPARTICLES ROOM-TEMPERATURE HIGH-PERFORMANCE DEHYDROGENATION GOLD STORAGE ELECTROOXIDATION |
| 通讯作者 | qin,yl |
| 英文摘要 | formic acid (fa) and methanol, as convenient hydrogen-containing materials, are most widely used for fuel cells. however, using suitable and low-cost catalysts to further improve their energy performance still is a matter of great significance. herein, pdco and pdco@pd nanocatalysts (ncs) are successfully prepared by the facile method. pd 3d binding energy decreases due to the presence of co. consequently, pdco@pd ncs exhibit high catalytic activity and selectivity toward fa dehydrogenation at room temperature. the gas-generation rate at 30 min is 65.4 lh(-1)g(-1). pdco/c has the worst catalytic performance in this reaction, despite the fact that it has a high gas-generation rate in the initial 30 min. furthermore, both pdco and pdco@pd ncs have enhanced electrocatalytic performance toward methanol oxidation. their maximum currents are 966 and 1205 mamg(-1), respectively, which is much higher than monometallic pd/c. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/64628]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qin,Yu-ling,Liu,Ya-cheng,Liang,Fei,et al. Preparation of Pd-Co-Based Nanocatalysts and Their Superior Applications in Formic Acid Decomposition and Methanol Oxidation[J]. chemsuschem,2015,8(2):260-263. |
| APA | Qin,Yu-ling,Liu,Ya-cheng,Liang,Fei,&Wang,Li-min.(2015).Preparation of Pd-Co-Based Nanocatalysts and Their Superior Applications in Formic Acid Decomposition and Methanol Oxidation.chemsuschem,8(2),260-263. |
| MLA | Qin,Yu-ling,et al."Preparation of Pd-Co-Based Nanocatalysts and Their Superior Applications in Formic Acid Decomposition and Methanol Oxidation".chemsuschem 8.2(2015):260-263. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。