Porous CoP concave polyhedron electrocatalysts synthesized from metal-organic frameworks with enhanced electrochemical properties for hydrogen evolution
文献类型：期刊论文
| 作者 | Xu,Miao; Han,Lei; Han,Yujie; Yu,You; Zhai,Junfeng; Dong,Shaojun |
| 刊名 | journal of materials chemistry a
 |
| 出版日期 | 2015 |
| 卷号 | 3期号:43页码:21471-21477 |
| 关键词 | PHOSPHIDE NANOPARTICLES NANOWIRE ARRAYS WATER EFFICIENT MOLYBDENUM CATALYSTS NANOSHEETS CATHODE CARBON ACID |
| 通讯作者 | dong,sj |
| 英文摘要 | developing highly efficient and low-cost noble metal-free catalysts toward hydrogen evolution from water splitting is an attractive alternative strategy to solve the ever-increasing environmental contamination and energy demand. herein, a porous cop electrocatalyst with a concave polyhedron (cph) structure was facilely prepared by a topological conversion strategy using co-mof (zif-67) polyhedrons as the precursor. the morphology of co-mofs is well inherited by the as-prepared cop sample due to the multi-step calcination process at low temperature, which results in the formation of a porous structure. compared with the contrastive cop nanoparticles (nps), the obtained porous cop cph electrocatalyst exhibits a remarkably enhanced electrocatalytic performance with a current density of 10 ma cm(-2) at an overpotential of 133 mv and a superior durability for the hydrogen evolution reaction (her) in acid media. a small tafel slope of ca. 51 mv dec(-1) reveals a volmer-heyrovsky mechanism during the her. this work provided a new insight to fabricate morphology-controlled transition metal phosphides with a porous structure via topological conversion, which have importantly potential applications, such as electrocatalysis, photocatalysis and sensors, thanks to their porosity and controllability. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000364020400009 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/64651]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xu,Miao,Han,Lei,Han,Yujie,et al. Porous CoP concave polyhedron electrocatalysts synthesized from metal-organic frameworks with enhanced electrochemical properties for hydrogen evolution[J]. journal of materials chemistry a,2015,3(43):21471-21477. |
| APA | Xu,Miao,Han,Lei,Han,Yujie,Yu,You,Zhai,Junfeng,&Dong,Shaojun.(2015).Porous CoP concave polyhedron electrocatalysts synthesized from metal-organic frameworks with enhanced electrochemical properties for hydrogen evolution.journal of materials chemistry a,3(43),21471-21477. |
| MLA | Xu,Miao,et al."Porous CoP concave polyhedron electrocatalysts synthesized from metal-organic frameworks with enhanced electrochemical properties for hydrogen evolution".journal of materials chemistry a 3.43(2015):21471-21477. |
入库方式： OAI收割
来源：长春应用化学研究所
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