中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Carbon with ultrahigh capacitance when graphene paper meets K3Fe(CN)(6)

文献类型:期刊论文

作者Chen,Kunfeng; Liu,Fei; Xue,Dongfeng; Komarneni,Sridhar
刊名nanoscale
出版日期2015
卷号7期号:2页码:432-439
关键词ELECTROCHEMICAL ENERGY-STORAGE ELECTRODE MATERIALS HIGH-PERFORMANCE SUPERCAPACITORS CRYSTALLIZATION CHARGE
通讯作者xue,df
英文摘要for the first time, we have shown a novel supercapacitor system with a graphene paper electrode in the redox-electrolyte of k3fe(cn)(6) based on the system-level design principle. by combining electric double-layer capacitance and pseudocapacitance, the specific capacitance could be increased 5-fold compared with the conventional electrode-electrolyte system. this large improvement is attributed to the additional redox reactions on the graphene paper electrode via the constituent ions of k3fe(cn)(6) in the redox-electrolyte, during which the discharge process is highly enhanced. more importantly, the potential interval could reach as high as 1.6 v beyond the limited operating voltage of water (similar to 1.23 v). after 5000 continuous cycles, 94% of the initial capacitance was retained. the newly designed novel supercapacitor system is binder-free, conducting additive-free and can deliver higher capacitance. this designed graphene-paper-electrode/redox-electrolyte system can provide a versatile strategy for high-capacitance supercapacitor systems.
收录类别SCI
语种英语
公开日期2016-05-03
源URL[http://ir.ciac.jl.cn/handle/322003/64656]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Chen,Kunfeng,Liu,Fei,Xue,Dongfeng,et al. Carbon with ultrahigh capacitance when graphene paper meets K3Fe(CN)(6)[J]. nanoscale,2015,7(2):432-439.
APA Chen,Kunfeng,Liu,Fei,Xue,Dongfeng,&Komarneni,Sridhar.(2015).Carbon with ultrahigh capacitance when graphene paper meets K3Fe(CN)(6).nanoscale,7(2),432-439.
MLA Chen,Kunfeng,et al."Carbon with ultrahigh capacitance when graphene paper meets K3Fe(CN)(6)".nanoscale 7.2(2015):432-439.

入库方式: OAI收割

来源:长春应用化学研究所

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