Carbon with ultrahigh capacitance when graphene paper meets K3Fe(CN)(6)
文献类型:期刊论文
作者 | Chen,Kunfeng; Liu,Fei; Xue,Dongfeng; Komarneni,Sridhar |
刊名 | nanoscale
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出版日期 | 2015 |
卷号 | 7期号:2页码:432-439 |
关键词 | ELECTROCHEMICAL ENERGY-STORAGE ELECTRODE MATERIALS HIGH-PERFORMANCE SUPERCAPACITORS CRYSTALLIZATION CHARGE |
通讯作者 | xue,df |
英文摘要 | for the first time, we have shown a novel supercapacitor system with a graphene paper electrode in the redox-electrolyte of k3fe(cn)(6) based on the system-level design principle. by combining electric double-layer capacitance and pseudocapacitance, the specific capacitance could be increased 5-fold compared with the conventional electrode-electrolyte system. this large improvement is attributed to the additional redox reactions on the graphene paper electrode via the constituent ions of k3fe(cn)(6) in the redox-electrolyte, during which the discharge process is highly enhanced. more importantly, the potential interval could reach as high as 1.6 v beyond the limited operating voltage of water (similar to 1.23 v). after 5000 continuous cycles, 94% of the initial capacitance was retained. the newly designed novel supercapacitor system is binder-free, conducting additive-free and can deliver higher capacitance. this designed graphene-paper-electrode/redox-electrolyte system can provide a versatile strategy for high-capacitance supercapacitor systems. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2016-05-03 |
源URL | [http://ir.ciac.jl.cn/handle/322003/64656] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Chen,Kunfeng,Liu,Fei,Xue,Dongfeng,et al. Carbon with ultrahigh capacitance when graphene paper meets K3Fe(CN)(6)[J]. nanoscale,2015,7(2):432-439. |
APA | Chen,Kunfeng,Liu,Fei,Xue,Dongfeng,&Komarneni,Sridhar.(2015).Carbon with ultrahigh capacitance when graphene paper meets K3Fe(CN)(6).nanoscale,7(2),432-439. |
MLA | Chen,Kunfeng,et al."Carbon with ultrahigh capacitance when graphene paper meets K3Fe(CN)(6)".nanoscale 7.2(2015):432-439. |
入库方式: OAI收割
来源:长春应用化学研究所
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