Enhanced pervaporation dehydration performance of ultrathin hybrid membrane by incorporating bioinspired multifunctional modifier and TiCl4 into chitosan
文献类型：期刊论文
| 作者 | Zhao, J; Wang, F; Pan, FS; Zhang, MX; Yang, XY; Li, P; Jiang, ZY; Zhang, P; Cao, XZ; Wang, BY;张鹏(正) |
| 刊名 | JOURNAL OF MEMBRANE SCIENCE
 |
| 出版日期 | 2013 |
| 卷号 | 446页码:395-404 |
| 关键词 | Ultrathin hybrid membrane Bioinspired multifunctional modifier Metal-organic coordination Swelling resistance Pervaporation dehydration |
| 英文摘要 | 3-(3,4-Dihydroxyphenyl)propionic acid (DHPPA) was introduced as a bioinspired multifunctional modifier to mediate the in situ sol-gel reaction of TiCl4 within chitosan (CS) matrix through metal organic coordination. Ultrathin, robust chitosan-titania hybrid membranes were obtained in a facile way. The morphology, chemical and physical structures, as well as the hydrophilicity and thermal stability of hybrid membranes were extensively characterized. An ethanol/water mixture was chosen as a model system to evaluate the swelling resistance property and pervaporation dehydration performance of the hybrid membranes. The simultaneous enhancement of hydrophilicity and swelling resistance was achieved clue to the presence of numerous carboxyl groups and the stable hybrid structure. The multiple interfacial interactions between polymeric and inorganic phases, as well as the steric effect of the bioinspired modifier, led to significant pervaporation performance enhancement of CS membrane. When the mass ratio of TiCl4 to CS was 14 wt%, the hybrid membrane exhibited the optimal pervaporation performance with a permeation flux of 1403 g/(m(2) h) and a separation factor of 730 for 90 wt% ethanol aqueous solution at 350 K. The operation stability was also testified in long term pervaporation separation test. (C) 2013 Elsevier B.V. All rights reserved. |
| 学科主题 | Engineering; Polymer Science |
| 收录类别 | SCI |
| WOS记录号 | WOS:000324308500043 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/223968]  |
| 专题 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Zhao, J,Wang, F,Pan, FS,et al. Enhanced pervaporation dehydration performance of ultrathin hybrid membrane by incorporating bioinspired multifunctional modifier and TiCl4 into chitosan[J]. JOURNAL OF MEMBRANE SCIENCE,2013,446:395-404. |
| APA | Zhao, J.,Wang, F.,Pan, FS.,Zhang, MX.,Yang, XY.,...&王宝义.(2013).Enhanced pervaporation dehydration performance of ultrathin hybrid membrane by incorporating bioinspired multifunctional modifier and TiCl4 into chitosan.JOURNAL OF MEMBRANE SCIENCE,446,395-404. |
| MLA | Zhao, J,et al."Enhanced pervaporation dehydration performance of ultrathin hybrid membrane by incorporating bioinspired multifunctional modifier and TiCl4 into chitosan".JOURNAL OF MEMBRANE SCIENCE 446(2013):395-404. |
入库方式： OAI收割
来源：高能物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。