中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Determination of estrogens and estrogenic activities in water from three rivers in Tianjin, China

文献类型:期刊论文

作者Rao, KF; Lei, BL; 李娜(多); Li, N; Ma, M; Wang, ZJ
刊名JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
出版日期2013
卷号25期号:6页码:1164-1171
关键词river water endocrine disrupting compounds (EDCs) yeast assay bioassay
英文摘要Studies on estrogenic disrupting compounds (EDCs) occurrence and identification of main responsible compounds in river water discharged into the sea are of significance. In the present research, we screened estrogenic activities of 10 river water samples from 3 main rivers discharged into Bohai Sea in Tianjin using a recombinant two-hybrid yeast assay and chemical analysis by gas chromatography-mass spectrometry. All sample extracts induced significant estrogenic activity, with 17 beta-estradiol equivalents (EEQ) of raw water ranging from 5.72 to 59.06 ng/L. Six most concerned EDCs in the river water samples including estrone, 17 beta-estradiol, 17 alpha-ethinylestradiol, estriol, diethylstilbestrol and estradiol valerate were determined, with their concentrations up to 50.70, 31.40, 24.40, 37.20, 2.56, and 8.47 ng/L, respectively. Through causality analysis by comparing the EEQ values of yeast assay and chemical analysis, 17 alpha-ethinylestradiol and 17 beta-estradiol were identified as the main contributors to the estrogenic effects of the river samples, accounting for the whole estrogenic activities (62.99% to 185.66%), and estrogen antagonistic compounds might presented in the heavy polluted water samples. The proposed approach using both chemical analysis and bioassay could be used for identification and evaluation of the estrogenic activity of EDCs in river water.
学科主题Environmental Sciences & Ecology
收录类别SCI
WOS记录号WOS:000320749900015
公开日期2016-05-03
源URL[http://ir.ihep.ac.cn/handle/311005/224113]  
专题高能物理研究所_多学科研究中心
推荐引用方式
GB/T 7714
Rao, KF,Lei, BL,Li N,et al. Determination of estrogens and estrogenic activities in water from three rivers in Tianjin, China[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2013,25(6):1164-1171.
APA Rao, KF,Lei, BL,李娜,Li, N,Ma, M,&Wang, ZJ.(2013).Determination of estrogens and estrogenic activities in water from three rivers in Tianjin, China.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,25(6),1164-1171.
MLA Rao, KF,et al."Determination of estrogens and estrogenic activities in water from three rivers in Tianjin, China".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 25.6(2013):1164-1171.

入库方式: OAI收割

来源:高能物理研究所

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