Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions
文献类型：期刊论文
| 作者 | Shang, WT; Kang, XC; Ning, H; Zhang, JL; Zhang, XG; Wu, ZH; Mo, G; Xing, XQ; Han, BX;吴忠华; Mo G(默广)
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| 刊名 | LANGMUIR
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| 出版日期 | 2013 |
| 卷号 | 29期号:43页码:13168-13174 |
| 英文摘要 | In this work, the La-metal organic frameworks (La-MOFs) were synthesized using lanthanum(III) nitrate and 1,3,5-benzenetricarboxylic acid (BTC) in H2O-in-1-butyl-3-methylimidazolium hexafluorophosphate (bmimPF(6)), bmimPF(6)-in-water, and the bicontinuous microemulsions stabilized by surfactant TX-100. The MOFs prepared were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), thermal gravimetric analysis (TGA), and FT-IR methods, and the microstructures of the microemulsions in the H2O/bmimPF(6)/TX-100 system were studied by small-angle X-ray scattering (SXAS) technique. It was shown that the dispersed droplets in the water-in-bmimPF(6), bicontinuous and bmimPF6-in-water microemulsions were spherical, lamellar, and cylindrical, respectively. The shapes of the La-MOFs synthesized were similar to that of the droplets in the corresponding microemulsions. This indicated that the morphology of MOFs could be controlled by the microstructures of the microemulsions. On the basis of the systematic experimental results, the mechanism for controlling the morphology of the MOFs was proposed. |
| 学科主题 | Chemistry; Materials Science |
| 收录类别 | SCI |
| WOS记录号 | WOS:000326429500008 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/224343]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 推荐引用方式 GB/T 7714 | Shang, WT,Kang, XC,Ning, H,et al. Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions[J]. LANGMUIR,2013,29(43):13168-13174. |
| APA | Shang, WT.,Kang, XC.,Ning, H.,Zhang, JL.,Zhang, XG.,...&邢雪青.(2013).Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions.LANGMUIR,29(43),13168-13174. |
| MLA | Shang, WT,et al."Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions".LANGMUIR 29.43(2013):13168-13174. |
入库方式： OAI收割
来源：高能物理研究所
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