Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19)
文献类型:期刊论文
作者 | Zhang, B; Zhang, Y; Chang GC(常广才)![]() |
刊名 | INORGANICA CHIMICA ACTA
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出版日期 | 2014 |
卷号 | 421页码:399-404 |
关键词 | Iron Oxalate Hydroxo Oxo Magnetism |
英文摘要 | Heterometallic yellow compound Ba-3[Fe(C2O4)(3)](2)(H2O)(12) (1) with mononuclear anion [Fe(C2O4)(3)(3-)] can be transformed to heterometallic red compound Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19) (2) with OH/O bridged tetranuclear anion [Fe4O(OH)(3)(C2O4)(8)(9-)] in the mother liquor. Ba2+ and Fe3+ form three-dimensional networks thorough oxalate anion and H2O molecules in 1 and 2. 1 is a paramagnet and a strong antiferromagnetic interaction as the ground state S = 0 exists in 2. (C) 2014 Elsevier B.V. All rights reserved. |
学科主题 | Chemistry |
收录类别 | SCI |
WOS记录号 | WOS:000341439300049 |
公开日期 | 2016-05-03 |
源URL | [http://ir.ihep.ac.cn/handle/311005/225039] ![]() |
专题 | 高能物理研究所_多学科研究中心 |
推荐引用方式 GB/T 7714 | Zhang, B,Zhang, Y,Chang GC,et al. Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19)[J]. INORGANICA CHIMICA ACTA,2014,421:399-404. |
APA | Zhang, B.,Zhang, Y.,常广才.,高增强;Chang, GC.,Gao, ZQ.,...&Zhu, DB.(2014).Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19).INORGANICA CHIMICA ACTA,421,399-404. |
MLA | Zhang, B,et al."Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19)".INORGANICA CHIMICA ACTA 421(2014):399-404. |
入库方式: OAI收割
来源:高能物理研究所
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