Electrochemical behavior of uranyl in ionic liquid 1-butyl-3-methylimidazolium chloride mixture with water
文献类型：期刊论文
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| 作者 | Tan XF(谭绪凤); Yuan LY(袁立永) ; Tan, XF; Yuan, LY; Nie, CM; Lui, K; Chai, ZF; Shi, WQ; Liu K(刘凯); Shi WQ(石伟群)
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| 刊名 | JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
 ; JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
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| 出版日期 | 2014 ; 2014 |
| 卷号 | 302期号:1页码:281-288 |
| 关键词 | Ionic liquid Cyclic voltammetry Electrochemical behavior Uranyl Ionic liquid Cyclic voltammetry Electrochemical behavior Uranyl |
| ISSN号 | 0236-5731 |
| DOI | 10.1007/s10967-014-3195-x |
| 英文摘要 | Electrochemical behaviors of U(VI) in 1-butyl-3-methylimidazolium chloride (C(4)MimCl) with various water contents investigated by chronopotentiometry and cyclic voltammetry. The electrochemical reduction of U(VI) was identified to follow two processes: a lower valence intermediate U(V) was initially formed at the potential of ca. -0.2 V(vs. Ag wire). Then, further deposition of UO2 was followed at around -0.8 V. Little amount of water (1-4 wt%) in C(4)MimCl, however, has an effect on the U(VI) reduction by changing the current density of the redox reaction and the diffusion coefficient of U(VI) in C(4)MimCl. The deposited product by potentiostatic electrolysis on the surface of stainless steel electrode was characterized by the scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and X-ray diffraction (XRD) methods. Although the electrodeposited black film was amorphous, the electrochemical reduced product of U(VI) can be still confirmed to be UO2 by XRD after the crystallization of the amorphous deposits at 1,073 K in nitrogen atmosphere.; Electrochemical behaviors of U(VI) in 1-butyl-3-methylimidazolium chloride (C(4)MimCl) with various water contents investigated by chronopotentiometry and cyclic voltammetry. The electrochemical reduction of U(VI) was identified to follow two processes: a lower valence intermediate U(V) was initially formed at the potential of ca. -0.2 V(vs. Ag wire). Then, further deposition of UO2 was followed at around -0.8 V. Little amount of water (1-4 wt%) in C(4)MimCl, however, has an effect on the U(VI) reduction by changing the current density of the redox reaction and the diffusion coefficient of U(VI) in C(4)MimCl. The deposited product by potentiostatic electrolysis on the surface of stainless steel electrode was characterized by the scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and X-ray diffraction (XRD) methods. Although the electrodeposited black film was amorphous, the electrochemical reduced product of U(VI) can be still confirmed to be UO2 by XRD after the crystallization of the amorphous deposits at 1,073 K in nitrogen atmosphere. |
| 学科主题 | Chemistry; Nuclear Science & Technology ; Chemistry; Nuclear Science & Technology |
| 收录类别 | SCI |
| 电子版国际标准刊号 | 1588-2780 |
| 语种 | 英语 |
| WOS记录号 | WOS:000342134800033 ; WOS:000342134800033 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/225162]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 推荐引用方式 GB/T 7714 | Tan XF,Yuan LY,Tan, XF,et al. Electrochemical behavior of uranyl in ionic liquid 1-butyl-3-methylimidazolium chloride mixture with water, Electrochemical behavior of uranyl in ionic liquid 1-butyl-3-methylimidazolium chloride mixture with water[J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,2014, 2014,302, 302(1):281-288, 281-288. |
| APA | 谭绪凤.,袁立永.,Tan, XF.,Yuan, LY.,Nie, CM.,...&石伟群.(2014).Electrochemical behavior of uranyl in ionic liquid 1-butyl-3-methylimidazolium chloride mixture with water.JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,302(1),281-288. |
| MLA | 谭绪凤,et al."Electrochemical behavior of uranyl in ionic liquid 1-butyl-3-methylimidazolium chloride mixture with water".JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY 302.1(2014):281-288. |
入库方式： OAI收割
来源：高能物理研究所
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