One-Step Synthesis of Highly Efficient Nanocatalysts on the Supports with Hierarchical Pores Using Porous Ionic Liquid-Water Gel
文献类型：期刊论文
| 作者 | Kang, XC; Zhang, JL; Shang, WT; Wu, TB; Zhang, P; Han, BX; Wu, ZH; Mo, G; Xing, XQ;吴忠华; Mo G(默广)
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| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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| 出版日期 | 2014 |
| 卷号 | 136期号:10页码:3768-3771 |
| 英文摘要 | Stable porous ionic liquid-water gel induced by inorganic salts was created for the first time. The porous gel was used to develop a one-step method to synthesize supported metal nanocatalysts. Au/SiO2, Ru/SiO2, Pd/Cu(2-pymo)(2) metal-organic framework (Cu-MOF), and Au/polyacrylamide (PAM) were synthesized, in which the supports had hierarchical meso- and macropores, the size of the metal nanocatalysts could be very small (<1 nm), and the size distribution was very narrow even when the metal loading amount was as high as 8 wt %. The catalysts were extremely active, selective, and stable for oxidative esterification of benzyl alcohol to methyl benzoate, benzene hydrogenation to cyclohexane, and oxidation of benzyl alcohol to benzaldehyde because they combined the advantages of the nanocatalysts of small size and hierarchical porosity of the supports. In addition, this method is very simple. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| WOS记录号 | WOS:000332922600015 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/225172]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 推荐引用方式 GB/T 7714 | Kang, XC,Zhang, JL,Shang, WT,et al. One-Step Synthesis of Highly Efficient Nanocatalysts on the Supports with Hierarchical Pores Using Porous Ionic Liquid-Water Gel[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2014,136(10):3768-3771. |
| APA | Kang, XC.,Zhang, JL.,Shang, WT.,Wu, TB.,Zhang, P.,...&邢雪青.(2014).One-Step Synthesis of Highly Efficient Nanocatalysts on the Supports with Hierarchical Pores Using Porous Ionic Liquid-Water Gel.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,136(10),3768-3771. |
| MLA | Kang, XC,et al."One-Step Synthesis of Highly Efficient Nanocatalysts on the Supports with Hierarchical Pores Using Porous Ionic Liquid-Water Gel".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 136.10(2014):3768-3771. |
入库方式： OAI收割
来源：高能物理研究所
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