Highly efficient photodimerization of olefins in a nanotemplate on HOPG by scanning tunneling microscopy
文献类型：期刊论文
| 作者 | Xue, JD; Xu, J; Hu, FY; Liao, LY; Li, M; Duan, WB; Zeng, QD; Wang, C;李敏 |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2014 |
| 卷号 | 16期号:47页码:25765-25769 |
| 英文摘要 | Efficient photochemical reactions on a surface are of great importance for their potential applications in optoelectronic devices. In this work, a highly efficient photodimerization reaction of an olefin cocrystal built from two trans-1,2-bis(4-pyridyl) ethylenes (4,4'-bpe) and two isophthalic acid molecules via N center dot center dot center dot H-O hydrogen bonds in between was achieved in a nanotemplate on a highly oriented pyrolytic graphite (HOPG) surface. 4,4'-Bpe molecules first undergo the trans-cis isomerization followed by [2+2] photodimerization in the nanotemplate on HOPG upon UV irradiation. The efficiency of the isomerization as well as the photodimerization in the presence of the nanotemplate is much higher than that in its absence. These results provide a facile way to achieve highly efficient photodimerization of olefins on a large scale on surfaces. |
| 学科主题 | Chemistry; Physics |
| 收录类别 | SCI |
| WOS记录号 | WOS:000345208200013 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/225254]  |
| 专题 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Xue, JD,Xu, J,Hu, FY,et al. Highly efficient photodimerization of olefins in a nanotemplate on HOPG by scanning tunneling microscopy[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2014,16(47):25765-25769. |
| APA | Xue, JD.,Xu, J.,Hu, FY.,Liao, LY.,Li, M.,...&Wang, C；李敏.(2014).Highly efficient photodimerization of olefins in a nanotemplate on HOPG by scanning tunneling microscopy.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,16(47),25765-25769. |
| MLA | Xue, JD,et al."Highly efficient photodimerization of olefins in a nanotemplate on HOPG by scanning tunneling microscopy".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 16.47(2014):25765-25769. |
入库方式： OAI收割
来源：高能物理研究所
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