Systematic investigation on Cadmium-incorporation in Li2FeSiO4/C cathode material for lithium-ion batteries
文献类型：期刊论文
| 作者 | Zhang, LL; Duan, S; Yang, XL; Liang, G; Huang, YH; Cao, XZ; Yang, J; Ni, SB; Li, M;曹兴忠; Yang J(杨静)
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| 刊名 | SCIENTIFIC REPORTS
 |
| 出版日期 | 2014 |
| 卷号 | 4页码:5064 |
| 英文摘要 | Cadmium-incorporated Li2FeSiO4/C composites have been successfully synthesized by a solid-state reaction assisted with refluxing. The effect and mechanism of Cd-modification on the electrochemical performance of Li2FeSiO4/C were investigated in detail by X-ray powder diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, Raman spectra, transmission electron microscopy, positron annihilation lifetime spectroscopy and Doppler broadening spectrum, and electrochemical measurements. The results show that Cd not only exists in an amorphous state of CdO on the surface of LFS particles, but also enters into the crystal lattice of LFS. Positron annihilation lifetime spectroscopy and Doppler broadening spectrum analyses verify that Cd-incorporation increases the defect concentration and the electronic conductivity of LFS, thus improve the Li+-ion diffusion process. Furthermore, our electrochemical measurements verify that an appropriate amount of Cd-incorporation can achieve a satisfied electrochemical performance for LFS/C cathode material. |
| 学科主题 | Science & Technology - Other Topics |
| 收录类别 | SCI |
| WOS记录号 | WOS:000336364500006 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/225369]  |
| 专题 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Zhang, LL,Duan, S,Yang, XL,et al. Systematic investigation on Cadmium-incorporation in Li2FeSiO4/C cathode material for lithium-ion batteries[J]. SCIENTIFIC REPORTS,2014,4:5064. |
| APA | Zhang, LL.,Duan, S.,Yang, XL.,Liang, G.,Huang, YH.,...&杨静.(2014).Systematic investigation on Cadmium-incorporation in Li2FeSiO4/C cathode material for lithium-ion batteries.SCIENTIFIC REPORTS,4,5064. |
| MLA | Zhang, LL,et al."Systematic investigation on Cadmium-incorporation in Li2FeSiO4/C cathode material for lithium-ion batteries".SCIENTIFIC REPORTS 4(2014):5064. |
入库方式： OAI收割
来源：高能物理研究所
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