The 4f5d configuration and VUV absorption of Pr3+ in YPO4
文献类型：期刊论文
| 作者 | Huang, SH; You, FT; Meng, CX; Wang, DW; Tao, Y; Zhang, GB; Tao Y(陶冶)
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| 刊名 | JOURNAL OF LUMINESCENCE
 |
| 出版日期 | 2007 |
| 卷号 | 122页码:#REF! |
| 关键词 | Pr3+ 4f5d configuration VUV spectrum |
| 通讯作者 | Huang, SH (reprint author), Beijing Jiaotong Univ, Key Lab Luminescence & Opt Informat, Inst Optoelect Technol, Beijing 100044, Peoples R China. |
| 英文摘要 | Crystal field interaction of the 5d electron [H-CF(5d)] and the Coulomb interaction between the 5d and the 4f electrons [H-C(fd)] are the most important interactions in determining the structure of the 4f5d configuration of Pr3+ in solids. Energy levels of the 4f5d configuration in YPO4:Pr were calculated by diagonalizing the simplified Hamiltonian H-CF(5d) + H-C(fd). Coulomb exchange interaction compresses the extension of the triplet states, while expands that of the singlet states. Thus, for the triplet states, H-C(fd) could be considered approximately as a perturbation to H-CF(5d). Since the ground state of the 4 configuration is a triplet, the triplet state structure in the 4f5d configuration determines the spectroscopic properties of the ground state absorption. Absorption spectrum calculated by using the obtained 4f5d wave functions is comparable with the experimental ones. (c) 2006 Elsevier B.V. All rights reserved. |
| 学科主题 | Optics |
| 类目[WOS] | Optics |
| 收录类别 | SCI |
| WOS记录号 | WOS:000242991900011 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/225579]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 推荐引用方式 GB/T 7714 | Huang, SH,You, FT,Meng, CX,et al. The 4f5d configuration and VUV absorption of Pr3+ in YPO4[J]. JOURNAL OF LUMINESCENCE,2007,122:#REF!. |
| APA | Huang, SH.,You, FT.,Meng, CX.,Wang, DW.,Tao, Y.,...&陶冶.(2007).The 4f5d configuration and VUV absorption of Pr3+ in YPO4.JOURNAL OF LUMINESCENCE,122,#REF!. |
| MLA | Huang, SH,et al."The 4f5d configuration and VUV absorption of Pr3+ in YPO4".JOURNAL OF LUMINESCENCE 122(2007):#REF!. |
入库方式： OAI收割
来源：高能物理研究所
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