The decolorization of Acid Orange II in non-homogeneous Fenton reaction catalyzed by natural vanadium-titanium magnetite
文献类型：期刊论文
| ; | |
| 作者 | Liang, XL; Zhong, YH; Zhu, SY; Zhu, JX; Yuan, P; He, HP; Zhang, J; Zhang J(张静) |
| 刊名 | JOURNAL OF HAZARDOUS MATERIALS
 ; JOURNAL OF HAZARDOUS MATERIALS
|
| 出版日期 | 2010 ; 2010 |
| 卷号 | 181期号:1-3页码:#REF! |
| 关键词 | Natural vanadium-titanium magnetite Non-homogeneous Fenton reaction Degradation Acid Orange II Catalyst Natural vanadium-titanium magnetite Non-homogeneous Fenton reaction Degradation Acid Orange II Catalyst |
| DOI | 10.1016/j.jhazmat.2010.04.101 |
| 通讯作者 | He, HP (reprint author), Chinese Acad Sci, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China. ; He, HP (reprint author), Chinese Acad Sci, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China. |
| 文献子类 | Article |
| 英文摘要 | The catalytic activity of natural vanadium-titanium magnetite was investigated in the decolorization of Acid Orange II by non-homogeneous Fenton process. The natural catalysts purified by magnetic separation were characterized using X-ray diffraction (XRD), polarizing microscope. X-ray absorption fine structure (XAFS) analysis and Mossbauer spectroscopy. The obtained results show that the natural samples after magnetic separation mainly contain titanomagnetite, with a small amount of ilmenite and chlorite. Titanomagnetite is doped with vanadium, whose the valency is mainly +3 and occupies the octahedral site. Batch decolorization studies were performed to evaluate the influences of various experimental parameters like initial pH, the amount of catalyst and initial concentration of hydrogen peroxide on the decolorization efficiency of Acid Orange II. The decolorization of the dye mainly relied on degradation. The degradation efficiency was strongly dependent on pH of the medium where it increased as the pH decreased in acid range. The increase of catalyst and hydrogen peroxide could accelerate the degradation. The catalytic property of natural vanadium-titanium magnetite in the degradation of Acid Orange II was stronger than that of synthetic magnetite (Fe(3)O(4)). The catalytic activity of the natural samples was greatly related to the titanomagnetite content. The degradation process was dominated by heterogeneous Fenton reaction, complying with pseudo-first-order rate law. The natural catalyst has a good catalytic stability. (C) 2010 Elsevier B.V. All rights reserved.; The catalytic activity of natural vanadium-titanium magnetite was investigated in the decolorization of Acid Orange II by non-homogeneous Fenton process. The natural catalysts purified by magnetic separation were characterized using X-ray diffraction (XRD), polarizing microscope. X-ray absorption fine structure (XAFS) analysis and Mossbauer spectroscopy. The obtained results show that the natural samples after magnetic separation mainly contain titanomagnetite, with a small amount of ilmenite and chlorite. Titanomagnetite is doped with vanadium, whose the valency is mainly +3 and occupies the octahedral site. Batch decolorization studies were performed to evaluate the influences of various experimental parameters like initial pH, the amount of catalyst and initial concentration of hydrogen peroxide on the decolorization efficiency of Acid Orange II. The decolorization of the dye mainly relied on degradation. The degradation efficiency was strongly dependent on pH of the medium where it increased as the pH decreased in acid range. The increase of catalyst and hydrogen peroxide could accelerate the degradation. The catalytic property of natural vanadium-titanium magnetite in the degradation of Acid Orange II was stronger than that of synthetic magnetite (Fe(3)O(4)). The catalytic activity of the natural samples was greatly related to the titanomagnetite content. The degradation process was dominated by heterogeneous Fenton reaction, complying with pseudo-first-order rate law. The natural catalyst has a good catalytic stability. (C) 2010 Elsevier B.V. All rights reserved. |
| 学科主题 | Engineering; Environmental Sciences & Ecology ; Engineering; Environmental Sciences & Ecology |
| 类目[WOS] | Engineering, Environmental ; Engineering, Civil ; Environmental Sciences |
| 收录类别 | SCI |
| WOS记录号 | WOS:000280601300014 ; WOS:000280601300014 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/226239]  |
| 专题 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Liang, XL,Zhong, YH,Zhu, SY,et al. The decolorization of Acid Orange II in non-homogeneous Fenton reaction catalyzed by natural vanadium-titanium magnetite, The decolorization of Acid Orange II in non-homogeneous Fenton reaction catalyzed by natural vanadium-titanium magnetite[J]. JOURNAL OF HAZARDOUS MATERIALS, JOURNAL OF HAZARDOUS MATERIALS,2010, 2010,181, 181(1-3):#REF!, #REF!. |
| APA | Liang, XL.,Zhong, YH.,Zhu, SY.,Zhu, JX.,Yuan, P.,...&张静.(2010).The decolorization of Acid Orange II in non-homogeneous Fenton reaction catalyzed by natural vanadium-titanium magnetite.JOURNAL OF HAZARDOUS MATERIALS,181(1-3),#REF!. |
| MLA | Liang, XL,et al."The decolorization of Acid Orange II in non-homogeneous Fenton reaction catalyzed by natural vanadium-titanium magnetite".JOURNAL OF HAZARDOUS MATERIALS 181.1-3(2010):#REF!. |
入库方式： OAI收割
来源：高能物理研究所
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