Mechanism of gold activation in supported gold catalysts for CO oxidation
文献类型：期刊论文
| 作者 | Hao, ZP; An, LD; Wang, HL; Hu, TD; Hu TD(胡天斗)
|
| 刊名 | REACTION KINETICS AND CATALYSIS LETTERS
 |
| 出版日期 | 2000 |
| 卷号 | 70期号:1页码:#REF! |
| 关键词 | mechanism of gold activation gold catalyst catalytic active center |
| 通讯作者 | Hao, ZP (reprint author), Chinese Acad Sci, Res Ctr Eco Environm Sci, Beijing 100085, Peoples R China. |
| 英文摘要 | Based on the structure characterization of Au/Fe2O3 catalysts, the mechanism of gold activation in supported gold catalysts was proposed as follow: Au3+ d(8) 6s(0) (catalyst precursor) (activation treatment)-->Audelta+ d(10-delta)6s(1) (catalyst) The possible catalytic active state is the partially oxidized gold (Audelta+) with unoccupied outer d orbitals, similar to the outer d orbital structure of Pt. Thus "inert" gold can become very active for CO oxidation. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Physical |
| 收录类别 | SCI |
| WOS记录号 | WOS:000088613100021 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/226537]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 推荐引用方式 GB/T 7714 | Hao, ZP,An, LD,Wang, HL,et al. Mechanism of gold activation in supported gold catalysts for CO oxidation[J]. REACTION KINETICS AND CATALYSIS LETTERS,2000,70(1):#REF!. |
| APA | Hao, ZP,An, LD,Wang, HL,Hu, TD,&胡天斗.(2000).Mechanism of gold activation in supported gold catalysts for CO oxidation.REACTION KINETICS AND CATALYSIS LETTERS,70(1),#REF!. |
| MLA | Hao, ZP,et al."Mechanism of gold activation in supported gold catalysts for CO oxidation".REACTION KINETICS AND CATALYSIS LETTERS 70.1(2000):#REF!. |
入库方式： OAI收割
来源：高能物理研究所
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