Molecular-Level Insights into Intrinsic Peroxidase-Like Activity of Nanocarbon Oxides
文献类型：期刊论文
| 作者 | Zhao RS(赵瑞生); Zhao, RS; Gao XF(高兴发) ; Zhao, X; Gao, XF
|
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2015 |
| 卷号 | 21期号:3页码:960-964 |
| 关键词 | carboxyl density functional calculations nanocarbon oxides peroxidase reaction mechanism |
| 通讯作者 | 高兴发 |
| 英文摘要 | Nanocarbon oxides have been proved to possess great peroxidase-like activity, catalyzing the oxidation of many peroxidase substrates, such as 3,3,5,5-tetramethylbenzidine (TMB) and o-phenylenediamine dihydrochloride (OPD), accompanied by a significant color change. This chromogenic reaction is widely used to detect glucose and occult blood. The chromogenic reaction was intensively investigated with density functional theory and molecular-level insights into the nature of peroxidase-like activity were gained. A radical mechanism was unraveled and the carboxyl groups of nanocarbon oxides were identified as the reactive sites. Aromatic domains connected with the carboxyl groups were critical to the peroxidase-like activity. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 收录类别 | SCI ; EI |
| WOS记录号 | WOS:000347615200002 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/228151]  |
| 专题 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Zhao RS,Zhao, RS,Gao XF,et al. Molecular-Level Insights into Intrinsic Peroxidase-Like Activity of Nanocarbon Oxides[J]. CHEMISTRY-A EUROPEAN JOURNAL,2015,21(3):960-964. |
| APA | 赵瑞生,Zhao, RS,高兴发,Zhao, X,&Gao, XF.(2015).Molecular-Level Insights into Intrinsic Peroxidase-Like Activity of Nanocarbon Oxides.CHEMISTRY-A EUROPEAN JOURNAL,21(3),960-964. |
| MLA | 赵瑞生,et al."Molecular-Level Insights into Intrinsic Peroxidase-Like Activity of Nanocarbon Oxides".CHEMISTRY-A EUROPEAN JOURNAL 21.3(2015):960-964. |
入库方式： OAI收割
来源：高能物理研究所
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