Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports
文献类型：期刊论文
| 作者 | Kang, XC; Shang, WT; Zhu, QG; Zhang, JL; Jiang, T; Han, BX; Wu, ZH; Li, ZH; Xing, XQ; Wu ZH(吴忠华)
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| 刊名 | CHEMICAL SCIENCE
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| 出版日期 | 2015 |
| 卷号 | 6期号:3页码:1668-1675 |
| 英文摘要 | We proposed a strategy to synthesize mesoporous inorganic salt particles using the special properties of ionic liquid (IL) mixtures, and hollow mesoporous LaF3, NdF3, and YF3 particles were synthesized and characterized using different techniques. The size of the mesopores in the salt particles was about 4 nm, and the materials were full of crystal defects. The LaF3, NdF3 and YF3 particles were used as the catalysts for the cyanosilylation reaction of benzaldehyde using trimethylsilyl cyanide, and Ru/LaF3 and Ru/NdF3, in which Ru nanocatalysts were supported on the LaF3 and NdF3 particles with mesopores, were used to catalyze hydrogenations of benzene to cyclohexane and levulinic acid (LA) to g-valerolactone (GVL). It was discovered that the activities of these catalysts were unprecedentedly high for these reactions. Detailed study showed that both the crystal defects and the mesopores in the salt particles played crucial roles for the extremely high catalytic activity. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 收录类别 | SCI ; EI |
| WOS记录号 | WOS:000349832600008 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/228171]  |
| 专题 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Kang, XC,Shang, WT,Zhu, QG,et al. Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports[J]. CHEMICAL SCIENCE,2015,6(3):1668-1675. |
| APA | Kang, XC.,Shang, WT.,Zhu, QG.,Zhang, JL.,Jiang, T.,...&邢雪青.(2015).Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports.CHEMICAL SCIENCE,6(3),1668-1675. |
| MLA | Kang, XC,et al."Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports".CHEMICAL SCIENCE 6.3(2015):1668-1675. |
入库方式： OAI收割
来源：高能物理研究所
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