Elevated pervaporation performance of polysiloxane membrane using channels and active sites of metal organic framework CuBTC
文献类型：期刊论文
| 作者 | Yu, SN; Jiang, ZY; Ding, H; Pan, FS; Wang, BY; Yang, J; Cao, XZ; Wang BY(王宝义) ; Yang J(杨静); Cao XZ(曹兴忠)
|
| 刊名 | JOURNAL OF MEMBRANE SCIENCE
 |
| 出版日期 | 2015 |
| 卷号 | 481页码:73-81 |
| 关键词 | Polydimethyl siloxane Metal organic framework Hybrid membrane Pervaporation Gasoline desulfurization |
| 英文摘要 | Hybrid membranes with polydimethyl siloxane (PDMS) as the polymer matrix and metal organic framework (MOF) CuBTC ([Cu-3(BTC)(2)]) as the filler were fabricated and applied in pervaporative separation of thiophene from model gasoline. CuBTC submicroparticles with size of 02-0.3 mu m were synthesized through a facile method at room temperature. The morphology, crystal structure and pore parameters of CuBTC, together with the morphology, functional groups, thermal and mechanical property, free volume characteristics, sorption and separation performance of PDMS-CuBTC hybrid membranes were studied. Primary functions of CuBTC particles are summarized as follows: (i) the channels of CuBTC provide expressways with low resistance for the transport of permeates; (ii) the submicroparticles interfere with the packing of PDMS chains, generating extra free volume of the membrane; (iii) the active metal sites of CuBTC facilitate the transport of thiophene; and (iv) the channels of CuBTC sieve thiophene from the bulk of model gasoline. As a result, the normalized flux and selectivity of PDMS membranes are elevated simultaneously. The optimal separation performance is achieved when the weight ratio of normal CuBTC to PDMS reaches 8%, with a permeation flux of 194.2 kg mu m/(m(2) h) and an enrichment factor of 52 (increase by 100% and 750 compared with PDMS control membrane, respectively). (C) 2015 Elsevier B.V. All rights reserved. |
| 学科主题 | Engineering; Polymer Science |
| 类目[WOS] | Engineering, Chemical ; Polymer Science |
| 收录类别 | SCI ; EI |
| WOS记录号 | WOS:000350856400009 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/228220]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 推荐引用方式 GB/T 7714 | Yu, SN,Jiang, ZY,Ding, H,et al. Elevated pervaporation performance of polysiloxane membrane using channels and active sites of metal organic framework CuBTC[J]. JOURNAL OF MEMBRANE SCIENCE,2015,481:73-81. |
| APA | Yu, SN.,Jiang, ZY.,Ding, H.,Pan, FS.,Wang, BY.,...&曹兴忠.(2015).Elevated pervaporation performance of polysiloxane membrane using channels and active sites of metal organic framework CuBTC.JOURNAL OF MEMBRANE SCIENCE,481,73-81. |
| MLA | Yu, SN,et al."Elevated pervaporation performance of polysiloxane membrane using channels and active sites of metal organic framework CuBTC".JOURNAL OF MEMBRANE SCIENCE 481(2015):73-81. |
入库方式： OAI收割
来源：高能物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。