Regioselective alkyl transfer from phosphonium ylides to functionalized polyfluoroarenes
文献类型：期刊论文
| 作者 | Lu W(路伟) ; Gao J(高娟); 刘蕾(多); Lu, W; Gao, J; Yang, JK; Liu, L; Zhao, YL; Wu, HC; Zhao YL(赵宇亮)
|
| 刊名 | CHEMICAL SCIENCE
 |
| 出版日期 | 2014 |
| 卷号 | 5期号:5页码:1934-1939 |
| 英文摘要 | We report an unprecedented alkyl transfer from phosphonium ylides to polyfluoroarenes in a highly regioselective manner. This reaction allows the introduction of a variety of alkyl groups to the para position of functionalized polyfluoroarenes under mild conditions. The process is found to be compatible with several electrophilic functional groups such as carboxyl, ester, amide and cyano groups. NMR spectroscopy studies and deuterated labeling experiments reveal that the reaction proceeds via an SNAr mechanism and the proton that is transferred to the alpha-carbon of the alkyl group during the last C-P bond breaking step is from water. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| WOS记录号 | WOS:000334492700032 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/224886]  |
| 专题 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Lu W,Gao J,Liu L,et al. Regioselective alkyl transfer from phosphonium ylides to functionalized polyfluoroarenes[J]. CHEMICAL SCIENCE,2014,5(5):1934-1939. |
| APA | 路伟.,高娟.,刘蕾.,Lu, W.,Gao, J.,...&吴海臣.(2014).Regioselective alkyl transfer from phosphonium ylides to functionalized polyfluoroarenes.CHEMICAL SCIENCE,5(5),1934-1939. |
| MLA | 路伟,et al."Regioselective alkyl transfer from phosphonium ylides to functionalized polyfluoroarenes".CHEMICAL SCIENCE 5.5(2014):1934-1939. |
入库方式： OAI收割
来源：高能物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。