New Three-Fold Interpenetrated Uranyl Organic Framework Constructed by Terephthalic Acid and Imidazole Derivative
文献类型：期刊论文
| 作者 | Chen F(陈飞) ; Wang CZ(王聪芝); Li ZJ(李子杰); Lan JH(蓝建慧); Chai ZF(柴之芳); Chen, F; Wang, CZ; Li, ZJ; Lan, JH; Ji, YQ
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| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:8页码:3829-3834 |
| 通讯作者 | 柴之芳 |
| 英文摘要 | A new 3-fold interpenetrated uranyl organic framework, UO2(bdc)(dmpi), was hydrothermally synthesized using 1,4-benzenedicarboxylic acid (H2bdc) and 1-(4-(1H-imidazol-1-yl)-2,5-dimethylphenyl)-1H-imidazole (dmpi). This framework, which was determined by synchrotron radiation X-ray, exhibited a new 3-fold interpenetrated (2,4)-connected topology with the Schlafli symbol of (12(6))(12)(2). Additionally, large incurvation happened to the bond angle of [O=U=O](2+), which was always arranged in a rigorous line. Computational results based on density functional theory (DFT) indicated that the bent geometry of uranyl in UO2(bdc)(dmpi) was mainly due to the higher charge populations in the valence 6d shells of uranium, rendered by the electronegative imidazoles. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Inorganic & Nuclear |
| 收录类别 | SCI |
| WOS记录号 | WOS:000353429500017 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/228522]  |
| 专题 | 高能物理研究所_院士 高能物理研究所_多学科研究中心 |
| 推荐引用方式 GB/T 7714 | Chen F,Wang CZ,Li ZJ,et al. New Three-Fold Interpenetrated Uranyl Organic Framework Constructed by Terephthalic Acid and Imidazole Derivative[J]. INORGANIC CHEMISTRY,2015,54(8):3829-3834. |
| APA | 陈飞.,王聪芝.,李子杰.,蓝建慧.,柴之芳.,...&Chai, ZF.(2015).New Three-Fold Interpenetrated Uranyl Organic Framework Constructed by Terephthalic Acid and Imidazole Derivative.INORGANIC CHEMISTRY,54(8),3829-3834. |
| MLA | 陈飞,et al."New Three-Fold Interpenetrated Uranyl Organic Framework Constructed by Terephthalic Acid and Imidazole Derivative".INORGANIC CHEMISTRY 54.8(2015):3829-3834. |
入库方式： OAI收割
来源：高能物理研究所
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