Progress in development and application of solid-state NMR for solid acid catalysis
文献类型：期刊论文
| 作者 | Zhang, HL(张海禄)
|
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2013-03 |
| 卷号 | 34期号:3页码:436-491 |
| 关键词 | Solid-state NMR spectroscopy Solid acid catalyst Probe molecule Acidity Catalytic reaction mechanism |
| 通讯作者 | Deng, F |
| 英文摘要 | Solid acid catalysts have been widely used in petrochemical industry and their catalytic activities are normally dictated by their acidities. Unlike conventional acidity characterization techniques such as titration, infrared, or temperature-programmed desorption, detailed acid features of solid acids, such as type, distribution, concentration, and strength of acid sites may be attained by advanced methods involving pertinent probe molecules and state-of-the-art solid-state nuclear magnetic resonance (SSNMR) techniques, i.e. double resonance and two-dimensional correlation spectroscopies. In addition, in situ solid-state NMR method is capable of probing the guest/host properties of the reactant at the active centers of the catalysts as well as the intermediate species formed during conversion. It provides direct experimental evidence for exploring the mechanism of catalytic reaction. In this report, the fundamental theory and the recent developments in solid-state NMR are reviewed with specific focus on relevant applications in structure and acidity characterization of solid acid catalysts and catalytic mechanisms. (C) 2013, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| 收录类别 | SCI ; EI |
| 语种 | 英语 |
| WOS记录号 | WOS:000317873600003 |
| 公开日期 | 2014-01-20 |
| 源URL | [http://ir.sinano.ac.cn/handle/332007/1528]  |
| 专题 | 苏州纳米技术与纳米仿生研究所_纳米仿生研究部_邓宗武团队 |
| 推荐引用方式 GB/T 7714 | Zhang, HL. Progress in development and application of solid-state NMR for solid acid catalysis[J]. CHINESE JOURNAL OF CATALYSIS,2013,34(3):436-491. |
| APA | Zhang, HL.(2013).Progress in development and application of solid-state NMR for solid acid catalysis.CHINESE JOURNAL OF CATALYSIS,34(3),436-491. |
| MLA | Zhang, HL."Progress in development and application of solid-state NMR for solid acid catalysis".CHINESE JOURNAL OF CATALYSIS 34.3(2013):436-491. |
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