Free-Standing, Single-Bilayer-Thick Polymeric Nanosheets via Spatially Confined Polymerization
文献类型：期刊论文
| 作者 | Wang D(王栋) ; Jin J(靳健)
|
| 刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
 |
| 出版日期 | 2014-06 |
| 卷号 | 35期号:11页码:1055-1060 |
| 关键词 | free-standing films lamellar polymeric nanosheets self-assembly spatially confined polymerization |
| 通讯作者 | 靳健 |
| 英文摘要 | Polymeric nanosheets organized by molecular building blocks bearing specifically oriented reactive groups provide abundant and versatile strategies for tailoring structure and chemical functionality periodically over extended length scales that complement graphene. Here we report the bulk synthesis of free-standing polymeric nanosheets via spatially confined polymerization from an elaborate 2D supramolecular system composed of two liquid-crystalline lamellar bilayer membranes of a self-assembled nonionic surfactant-dodecylglyceryl itaconate (DGI)-sandwiched by a water layer. By employing a covalent polymerization on the lamellar bilayer membranes, single-bilayer-thick (4.2 nm), and large area (greater than 100 mu m(2)) polymeric nanosheets of bilayer membranes are achieved. The polymeric nanosheets could serve as a well-defined 2D platform for post-functionalization for producing advanced hybrid materials by introducing the reactions on the hydroxyl groups at the head of DGI on the outer surfaces. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000337608800005 |
| 公开日期 | 2014-12-08 |
| 源URL | [http://ir.sinano.ac.cn/handle/332007/1665]  |
| 专题 | 苏州纳米技术与纳米仿生研究所_纳米仿生研究部_靳健团队 |
| 推荐引用方式 GB/T 7714 | Wang D,Jin J. Free-Standing, Single-Bilayer-Thick Polymeric Nanosheets via Spatially Confined Polymerization[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2014,35(11):1055-1060. |
| APA | Wang D,&Jin J.(2014).Free-Standing, Single-Bilayer-Thick Polymeric Nanosheets via Spatially Confined Polymerization.MACROMOLECULAR RAPID COMMUNICATIONS,35(11),1055-1060. |
| MLA | Wang D,et al."Free-Standing, Single-Bilayer-Thick Polymeric Nanosheets via Spatially Confined Polymerization".MACROMOLECULAR RAPID COMMUNICATIONS 35.11(2014):1055-1060. |
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