Acid-Induced Degradation and Ancillary Ligand Replacement of Biscyclometalated Iridium(III) Complexes
文献类型：期刊论文
| 作者 | Li, WF(李宛飞) ; Zhou, YY(周宇扬)
|
| 刊名 | CHEMPLUSCHEM
 |
| 出版日期 | 2013-05 |
| 卷号 | 78期号:5页码:413-418 |
| 关键词 | coordination chemistry iridium ligand effects N O ligands |
| 通讯作者 | Liu, Y*(刘扬) |
| 英文摘要 | Three biscyclometalated iridium(III) complexes with three different ancillary ligands have been investigated with respect to the final products of acid-induced transformation in coordinating or non-coordinating solvents. All of these complexes, represented as [Ir(LC boolean AND N)2LO boolean AND O] and [Ir(LC boolean AND N)2LN boolean AND O], are susceptible to acid attack, followed by the departure of the ancillary ligand, LO boolean AND O or LN boolean AND O. Depending on the coordinating ability of the solvent molecule and whether or not a coordinating anion exists, the final product will be either a solvento complex or a dichloro-bridged iridium(III) dimer. Although coexistence of the solvento complex and dichloro-bridged iridium(III) dimer was observed under certain conditions, the conversion of the solvento complex into the dichloro-bridged iridium(III) dimer has been proven. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000318802000005 |
| 公开日期 | 2013-12-31 |
| 源URL | [http://ir.sinano.ac.cn/handle/332007/1186]  |
| 专题 | 苏州纳米技术与纳米仿生研究所_纳米生物医学与安全研究部_离职团队 |
| 推荐引用方式 GB/T 7714 | Li, WF,Zhou, YY. Acid-Induced Degradation and Ancillary Ligand Replacement of Biscyclometalated Iridium(III) Complexes[J]. CHEMPLUSCHEM,2013,78(5):413-418. |
| APA | Li, WF,&Zhou, YY.(2013).Acid-Induced Degradation and Ancillary Ligand Replacement of Biscyclometalated Iridium(III) Complexes.CHEMPLUSCHEM,78(5),413-418. |
| MLA | Li, WF,et al."Acid-Induced Degradation and Ancillary Ligand Replacement of Biscyclometalated Iridium(III) Complexes".CHEMPLUSCHEM 78.5(2013):413-418. |
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