Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions
文献类型：期刊论文
| 作者 | Wang, WL (Wang, Wenlong) ; Zheng, AM (Zheng, Anmin) ; Zhao, PQ (Zhao, Peiqing) ; Xia, C (Xia, Chungu) ; Li, FW (李福伟) |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2014-01 |
| 卷号 | 4期号:1页码:321-327 |
| 关键词 | N-heterocyclic carbene porous organic polymers synthetic control alkyne hydration cross-coupling |
| 通讯作者 | Li, FW (李福伟) |
| 英文摘要 | The synthetic control and functions of porous organic polymers (POPs) with N-heterocyclic carbene gold(I) (Au-NHC@POPs) are described in this article. A series of Au-NHC@POPs with tunable physical properties such as surface area and pore size distribution were first synthesized via Sonogashira chemistry by differing monomer strut lengths and concentration during polymerization; a controllable transition from nonporous to microporous and the coexistence of micro- and mesoporous structures in the framework were realized by varying the monomer concentration. To explain this phenomenon, we put forward a model assumption of a branch-branch cross effect. Additionally, Au-NHC@POPs1 was found to have superior catalytic activity in alkyne hydration reactions, and the catalyst could be used six times with a slight loss of activity. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2014-12-19 |
| 源URL | [http://ir.sinano.ac.cn/handle/332007/1684]  |
| 专题 | 苏州纳米技术与纳米仿生研究所_先进材料研究部_离职团队 |
| 推荐引用方式 GB/T 7714 | Wang, WL ,Zheng, AM ,Zhao, PQ ,et al. Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions[J]. ACS CATALYSIS,2014,4(1):321-327. |
| APA | Wang, WL ,Zheng, AM ,Zhao, PQ ,Xia, C ,&Li, FW .(2014).Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions.ACS CATALYSIS,4(1),321-327. |
| MLA | Wang, WL ,et al."Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions".ACS CATALYSIS 4.1(2014):321-327. |
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