High energy density hybrid Mg2+/Li+ battery with superior ultra-low temperature performance
文献类型：期刊论文
| 作者 | Zhang, Zhonghua1,2; Xu, Huimin3; Cui, Zili1 ; Hu, Pu1; Chai, Jingchao1; Du, Huiping1; He, Jianjiang1; Zhang, Jianjun1; Zhou, Xinhong3; Han, Pengxian1
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| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
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| 出版日期 | 2016 |
| 卷号 | 4期号:6页码:2277-2285 |
| 英文摘要 | The development of high energy density rechargeable Mg-based batteries operating in a wide electrochemical window and ultra-low temperature remains a great challenge owing to parasitic side reactions between electrolytes and battery components when examined at high operating potentials (above 2.0 V vs. Mg2+/Mg). Herein we propose a flexible pyrolytic graphitic film (GF) as a reliable current collector of high-voltage cathodes for a hybrid Mg2+/Li+ battery within a pouch cell configuration. The utilization of such a highly electrochemical stable GF unlocks the critical bottleneck of incompatibility among all battery parts, especially parasitic corrosive reactions between electrolytes and currently available current collectors, which takes a big step forward towards the practical applications of Mg-based batteries. With an operating potential of 2.4 V, the hybrid Mg2+/Li+ battery designed by us can deliver a maximum energy density of 382.2 W h kg(-1), which significantly surpasses that of the conventional Mg battery (about 60 W h kg(-1)), and the Al battery (about 40 W h kg(-1)) as well as the state-of-the-art hybrid Na/Mg and Li/Mg batteries. The electrochemical property of the hybrid Mg2+/Li+ battery is also characterized by higher rate capability (68.8 mA h g(-1) at 3.0C), higher coulombic efficiency of 99.5%, and better cyclic stability (98% capacity retention after 200 cycles at 1.0C). In addition, the designed hybrid battery delivers excellent electrochemical performance at an ultra-low temperature of -40 degrees C, at which it retains 77% capacity compared to that of room temperature. Our strategy opens up a new possibility for widespread applications of graphitic current collectors towards high energy rechargeable Mg-based hybrid batteries, especially applied in polar regions, aerospace, and deep offshore waters. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Materials Science |
| 关键词[WOS] | RECHARGEABLE MAGNESIUM BATTERIES ; ELECTROLYTE-SOLUTIONS ; CURRENT COLLECTORS ; MG BATTERIES ; ION BATTERY ; CATHODE ; STABILITY ; CHEMISTRY ; CORROSION ; STORAGE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000369568700028 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/7974]  |
| 专题 | 青岛生物能源与过程研究所_仿生能源与储能系统团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Ind Energy Storage Res Inst, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100190, Peoples R China 3.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China 4.Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 102488, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zhonghua,Xu, Huimin,Cui, Zili,et al. High energy density hybrid Mg2+/Li+ battery with superior ultra-low temperature performance[J]. JOURNAL OF MATERIALS CHEMISTRY A,2016,4(6):2277-2285. |
| APA | Zhang, Zhonghua.,Xu, Huimin.,Cui, Zili.,Hu, Pu.,Chai, Jingchao.,...&Chen, Liquan.(2016).High energy density hybrid Mg2+/Li+ battery with superior ultra-low temperature performance.JOURNAL OF MATERIALS CHEMISTRY A,4(6),2277-2285. |
| MLA | Zhang, Zhonghua,et al."High energy density hybrid Mg2+/Li+ battery with superior ultra-low temperature performance".JOURNAL OF MATERIALS CHEMISTRY A 4.6(2016):2277-2285. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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