Highly efficient hydrogen evolution over Co(OH)(2) nanoparticles modified g-C3N4 co-sensitized by Eosin Y and Rose Bengal under Visible Light Irradiation
文献类型:期刊论文
作者 | Li Z(李振)1,2; Wu YQ(吴玉琪)1![]() ![]() ![]() ![]() |
刊名 | Applied Catalysis B: Environmental
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出版日期 | 2016 |
卷号 | 188页码:56-64 |
关键词 | Co(OH)(2) nanoparticles g-C3N4 Co-sensitized Highly efficient Hydrogen evolution Photocatalyst |
ISSN号 | 0926-3373 |
通讯作者 | 吕功煊 |
英文摘要 | In this work, non-noble metal cobalt hydroxide nanoparticles [Co(OH)2 NPs] implanted uniformly on graphitic carbon nitride (g-C3N4) as a co-catalyst for hydrogen evolution reaction (HER) by in-situ chemical deposition method were reported. After co-sensitized by Eosin Y (EY) and Rose Bengal (RB) dyes, this photocatalyst exhibited a comparatively low onset potential (0.26 V) for HER and high photocatalytic HER activity under visible light irradiation. The g-C3N4 not only provided a large area and nanoporous structure for the confined growth of Co(OH)2 NPs, but also greatly facilitated EY and RB (ER) molecules assembling on its surface, which promoted the charge transfer from dye to co-catalyst. The PL spectra and lifetime test showed the strong interaction between Co(OH)2 NPs and g-C3N4 could enhance the transferr rate of the photogenerated electron to reduce the carries recombination. About 431.9 μmol of hydrogen generated over ER co-sensitized Co(OH)2/C3N4 in 3 h. The apparent quantum efficiencies (AQE) of 29.6 and 27.3% were achieved at 520 nm and 550 nm over Co(OH)2/C3N4, respectively. In addition, this co-sensitized photocatalyst showed satisfied stability for HER, no remarkable decay of activity was observed in 900 min reaction. These results imply that Co(OH)2 is a stable and efficient cheaper co-catalyst for photo-HER. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the NSF of China (grant no. 21173242;21433007) |
语种 | 英语 |
WOS记录号 | WOS:000372677500007 |
源URL | [http://210.77.64.217/handle/362003/19493] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
通讯作者 | Lv GX(吕功煊); Lv GX(吕功煊) |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li Z,Wu YQ,Lu GX,et al. Highly efficient hydrogen evolution over Co(OH)(2) nanoparticles modified g-C3N4 co-sensitized by Eosin Y and Rose Bengal under Visible Light Irradiation[J]. Applied Catalysis B: Environmental,2016,188:56-64. |
APA | Li Z,Wu YQ,Lu GX,吕功煊,&吕功煊.(2016).Highly efficient hydrogen evolution over Co(OH)(2) nanoparticles modified g-C3N4 co-sensitized by Eosin Y and Rose Bengal under Visible Light Irradiation.Applied Catalysis B: Environmental,188,56-64. |
MLA | Li Z,et al."Highly efficient hydrogen evolution over Co(OH)(2) nanoparticles modified g-C3N4 co-sensitized by Eosin Y and Rose Bengal under Visible Light Irradiation".Applied Catalysis B: Environmental 188(2016):56-64. |
入库方式: OAI收割
来源:兰州化学物理研究所
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