Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2
文献类型：期刊论文
| 作者 | Shen DY(沈都益)1,2 ; Miao CX(苗成霞)1; Xu DQ(徐大乾)1; Xia CG(夏春谷)1; Sun W(孙伟)1
|
| 刊名 | Organic Letters
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:1页码:54-57 |
| ISSN号 | 1523-7060 |
| 通讯作者 | 孙伟 |
| 英文摘要 | The manganese complex Mn(S-PMB)(CF3SO3)2 was proven to be highly efficient in the catalytic oxidation of several benzylic and aliphatic secondary alcohols with H2O2 as the oxidant and acetic acid as the additive. A maximum turnover number of 4700 was achieved in the alcohol oxidation. In addition, the Hammett analysis unveiled the electrophilic nature of this manganese catalyst with N4 ligand. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Nos. 21133011;21373248) |
| 语种 | 英语 |
| 源URL | [http://210.77.64.217/handle/362003/19473]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China 2.University of Chinese Academy of Sciences, Beijing 100049, P. R. China |
| 推荐引用方式 GB/T 7714 | Shen DY,Miao CX,Xu DQ,et al. Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2[J]. Organic Letters,2015,17(1):54-57. |
| APA | Shen DY,Miao CX,Xu DQ,Xia CG,&Sun W.(2015).Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2.Organic Letters,17(1),54-57. |
| MLA | Shen DY,et al."Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2".Organic Letters 17.1(2015):54-57. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。