Tribological Properties of MACs-APS Films
文献类型：期刊论文
| 作者 | Wang, Yan-Bin1,3; Sun, Chu-Feng2,3; Su, Qiong3; Wang, Rong-Min1 |
| 刊名 | Journal of Macromolecular Science Part B Physics
 |
| 出版日期 | 2012 |
| 卷号 | 51期号:10页码:2064-2074 |
| 关键词 | films friction load-carrying MACs wear |
| ISSN号 | 0022-2348 |
| 通讯作者 | Wang, Rong-Min |
| 英文摘要 | Multiply-alkylated cyclopentanes (MACs) with different molecular structure were deposited on single crystal silicon wafers coated with a thin aminopropyltrimethoxylsilane (APS) film as an adhesive layer to form MACs-APS films. The thickness, wetting behavior and nano-scale morphologies of the films were characterized by means of ellipsometry, contact angle measurement, and atomic force microscopy (AFM). The friction and wear behaviors of the thin films sliding against a Si3N4 ball were examined on a UMT-2MT tribometer in a ball-on-disk contact mode. The worn surfaces of the MACs-APS films and the counterpart Si3N4 balls were investigated with a scanning electron microscope (SEM). It was found that the water contact angles on the MACs-APS film increased with the MACs alkyl chain-length. The MACs-APS film exhibited higher load-carrying capacity and better friction reduction and anti-wear behavior as compared with the APS film. This is suggested to occur because the APS acts as a strongly bonded lubricant phase and MACs as a mobile lubricant phase in the MACs-APS film. The increase of the chain-length of the alkyl substituent in the MACs compounds resulted in improved tribological properties of MACs-APS film. It is suggested that the longer alkyl chains are much more flexible and can dissipate the mechanical energy during the shearing process more easily than the short chain compounds. MACs with the longer chains have stronger chain-chain interactions and the larger MAC molecules have stronger intermolecular interactions, resulting in the good tribological properties of MACs-APS film. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Grant No. 51167017;50721602) |
| 语种 | 英语 |
| WOS记录号 | WOS:000308022800013 |
| 公开日期 | 2016-05-03 |
| 源URL | [http://210.77.64.217/handle/362003/19420]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 作者单位 | 1.NW Normal Univ, Minist Educ, Coll Chem & Chem Engn, Key Lab Ecoenvironm Related Polymer Mat, Lanzhou 730070, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 3.NW Nationalities Univ, Coll Chem Engn, Lanzhou, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yan-Bin,Sun, Chu-Feng,Su, Qiong,et al. Tribological Properties of MACs-APS Films[J]. Journal of Macromolecular Science Part B Physics,2012,51(10):2064-2074. |
| APA | Wang, Yan-Bin,Sun, Chu-Feng,Su, Qiong,&Wang, Rong-Min.(2012).Tribological Properties of MACs-APS Films.Journal of Macromolecular Science Part B Physics,51(10),2064-2074. |
| MLA | Wang, Yan-Bin,et al."Tribological Properties of MACs-APS Films".Journal of Macromolecular Science Part B Physics 51.10(2012):2064-2074. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。