Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions
文献类型：期刊论文
| 作者 | Guo, Ya-Fei; Xu, Bao-Hua; Li, Ting; Wang, Lei; Zhang, Suo-Jiang |
| 刊名 | ORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2016 |
| 卷号 | 3期号:1页码:47-52 |
| ISSN号 | 2052-4129 |
| 英文摘要 | The efficient cobalt(II) catalyzed oxidative alkoxylation of aldehydes, a method directly leading to the corresponding esters, is presented. Mechanism studies provide extensive insights into the cobalt mediated decomposition of TBHP in the presence of the iodide ion. The in situ generated hypoiodites (IO-/IO2-) mainly from conversion of I-3(-) to IO3- account for a cooperative effect with the oxygen centered radical species to make the important hydrogen abstraction of hemiacetal intermediates more selective, thereby offering high efficiency. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CATALYZED DIRECT ARYLATION ; CROSS-COUPLING REACTIONS ; C-H BOND ; TRANSITION-METALS ; AEROBIC OXIDATION ; AROMATIC IMINES ; CARBON-HYDROGEN ; BENZYL ALCOHOLS ; AMIDATION ; AMINES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000366864700007 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/20196]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Ya-Fei,Xu, Bao-Hua,Li, Ting,et al. Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions[J]. ORGANIC CHEMISTRY FRONTIERS,2016,3(1):47-52. |
| APA | Guo, Ya-Fei,Xu, Bao-Hua,Li, Ting,Wang, Lei,&Zhang, Suo-Jiang.(2016).Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions.ORGANIC CHEMISTRY FRONTIERS,3(1),47-52. |
| MLA | Guo, Ya-Fei,et al."Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions".ORGANIC CHEMISTRY FRONTIERS 3.1(2016):47-52. |
入库方式： OAI收割
来源：过程工程研究所
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