Chemical forms of the fluorine, chlorine, oxygen and carbon in coal fly ash and their correlations with mercury retention
文献类型：期刊论文
| 作者 | Deng, Shuang1,2; Shu, Yun2; Li, Songgeng3; Tian, Gang2; Huang, Jiayu2; Zhang, Fan2 |
| 刊名 | JOURNAL OF HAZARDOUS MATERIALS
 |
| 出版日期 | 2016-01-15 |
| 卷号 | 301期号:JAN页码:400-406 |
| 关键词 | Coal fly ash Surface functionality Chlorine Fluorine Mercury retention |
| ISSN号 | 0304-3894 |
| 英文摘要 | Fly ashes recovered from the particulate control devices at six pulverized coal boiler unites of China, are studied using an X-ray photoelectron spectroscopy (XPS) with a particular focus on the functionalities of fluorine (F), chlorine (Cl), carbon and oxygen on fly ash. It is found that the inorganic forms of F and Cl are predominant on the ash surface in comparison with their organics, and the proportion of organic Cl is relatively higher than that of organic F. Similar results are also obtained in the bulk by correlating the F and Cl contents with those of the unburnt carbon and other compositions in ash. Strong correlations of mercury retention with surface carbon-oxygen functional groups indicate that the C=O, OH/C-O and (O-C=O)-O on surface are of significant importance for mercury retention in fly ash. Their surface concentrations are related to coal type. The presence of Cl in fly ash helps with mercury retention. No obvious effect of F is observed. (C) 2015 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology ; Life Sciences & Biomedicine |
| 类目[WOS] | Engineering, Environmental ; Engineering, Civil ; Environmental Sciences |
| 研究领域[WOS] | Engineering ; Environmental Sciences & Ecology |
| 关键词[WOS] | FIRED POWER-PLANTS ; RAY PHOTOELECTRON-SPECTROSCOPY ; ELECTROSTATIC PRECIPITATORS ; EMISSION ; ELEMENTS ; CHINA ; COMBUSTION ; ADSORPTION ; SPECIATION ; SORBENTS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000367407200043 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/20250]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.State Key Lab Environm Criteria & Risk Assessment, Beijing, Peoples R China 2.Res Acad Environm Sci, Beijing 100012, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, Shuang,Shu, Yun,Li, Songgeng,et al. Chemical forms of the fluorine, chlorine, oxygen and carbon in coal fly ash and their correlations with mercury retention[J]. JOURNAL OF HAZARDOUS MATERIALS,2016,301(JAN):400-406. |
| APA | Deng, Shuang,Shu, Yun,Li, Songgeng,Tian, Gang,Huang, Jiayu,&Zhang, Fan.(2016).Chemical forms of the fluorine, chlorine, oxygen and carbon in coal fly ash and their correlations with mercury retention.JOURNAL OF HAZARDOUS MATERIALS,301(JAN),400-406. |
| MLA | Deng, Shuang,et al."Chemical forms of the fluorine, chlorine, oxygen and carbon in coal fly ash and their correlations with mercury retention".JOURNAL OF HAZARDOUS MATERIALS 301.JAN(2016):400-406. |
入库方式： OAI收割
来源：过程工程研究所
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