Thermodynamics and Separation Process for Quaternary Acrylic Systems
文献类型：期刊论文
| 作者 | Zuo, Cuncun; Li, Yaping; Li, Chunshan; Cao, Shasha; Yao, Haoyu; Zhang, Suojiang |
| 刊名 | AICHE JOURNAL
 |
| 出版日期 | 2016 |
| 卷号 | 62期号:1页码:228-240 |
| ISSN号 | 0001-1541 |
| 关键词 | methyl acrylate tridimensional VLE phase diagrams quaternary LLE phase diagrams thermodynamics separation |
| 英文摘要 | Vapor-liquid equilibrium (VLE) and liquid-liquid equilibrium (LLE) data of binary and ternary acrylic systems were systematically measured. Subsequently, VLLE phase diagrams of binary systems, tridimensional VLE phase diagrams of methyl acrylate (MA)-methanol (Me)-H2O ternary system, and quaternary LLE phase diagrams of MA-Me-H2O-methyl acetate (MeOAc) system were constructed. These diagrams clearly demonstrated the effects of temperature on phase equilibrium. The experimental data was fitted by the NRTL and UNIQUAC models, and the best-fitted parameters were used to predict interaction properties of ternary and quaternary mixture. Therefore, the phase equilibrium data were provided as reference for the design of acrylic systems rectification or extraction process. Residue curve was mapped out for MA-Me-H2O system through Aspen plus software. Finally, using thermodynamics and residue curve as theoretical basis, two novel separation processes were proposed and applied to the quaternary acrylic systems. (C) 2015 American Institute of Chemical Engineers |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | VAPOR-LIQUID-EQUILIBRIA ; ACETATE PLUS METHANOL ; METHYL ACETATE ; ACETIC-ACID ; INTERACTION PARAMETERS ; AZEOTROPIC MIXTURES ; PHASE-EQUILIBRIA ; IONIC LIQUIDS ; WATER ; DISTILLATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000367924600018 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/20269]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zuo, Cuncun,Li, Yaping,Li, Chunshan,et al. Thermodynamics and Separation Process for Quaternary Acrylic Systems[J]. AICHE JOURNAL,2016,62(1):228-240. |
| APA | Zuo, Cuncun,Li, Yaping,Li, Chunshan,Cao, Shasha,Yao, Haoyu,&Zhang, Suojiang.(2016).Thermodynamics and Separation Process for Quaternary Acrylic Systems.AICHE JOURNAL,62(1),228-240. |
| MLA | Zuo, Cuncun,et al."Thermodynamics and Separation Process for Quaternary Acrylic Systems".AICHE JOURNAL 62.1(2016):228-240. |
入库方式： OAI收割
来源：过程工程研究所
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