Electrodeposition of crystalline silicon directly from silicon tetrachloride in ionic liquid at low temperature
文献类型：期刊论文
| 作者 | Zhang, Junling; Chen, Shimou; Zhang, Haitao; Zhang, Suojiang; Yao, Xue; Shi, Zhaohui |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:15页码:12061-12067 |
| ISSN号 | 2046-2069 |
| 英文摘要 | Crystalline silicon (Si) is widely used in modern electronics. Si is commonly produced through a series of energy-intensive reactions (> 700 degrees C). It is thus urgent and significant to explore more economically and environmentally-benign synthetic strategies for crystalline Si at low temperature. In this contribution, we report an efficient method to prepare crystalline Si from silicon tetrachloride at the low temperature of 100 degrees C with an ionic liquid (IL) as electrolyte. Physicochemical characterization revealed that as-deposited crystalline Si with a diamond cubic crystal structure exhibited a dominant (111)-orientation. Moreover, in-depth insights into the growth mechanism of crystalline Si was shed light upon herein. Furthermore, the smart electrodepositing platform of crystalline Si from ILs would open up a new avenue for low-temperature metallurgy of Si. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ELECTROCHEMICAL REDUCTION ; ROOM-TEMPERATURE ; ALUMINUM ELECTRODEPOSITION ; BATTERIES ; CHLORIDE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000369545800018 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/20613]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Junling,Chen, Shimou,Zhang, Haitao,et al. Electrodeposition of crystalline silicon directly from silicon tetrachloride in ionic liquid at low temperature[J]. RSC ADVANCES,2016,6(15):12061-12067. |
| APA | Zhang, Junling,Chen, Shimou,Zhang, Haitao,Zhang, Suojiang,Yao, Xue,&Shi, Zhaohui.(2016).Electrodeposition of crystalline silicon directly from silicon tetrachloride in ionic liquid at low temperature.RSC ADVANCES,6(15),12061-12067. |
| MLA | Zhang, Junling,et al."Electrodeposition of crystalline silicon directly from silicon tetrachloride in ionic liquid at low temperature".RSC ADVANCES 6.15(2016):12061-12067. |
入库方式： OAI收割
来源：过程工程研究所
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