中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Enhanced lignin extraction process from steam exploded corn stalk

文献类型:期刊论文

作者Wang, Guanhua1,2; Chen, Hongzhang1
刊名SEPARATION AND PURIFICATION TECHNOLOGY
出版日期2016-01-08
卷号157期号:JAN页码:93-101
关键词Lignin alkaline extraction Steam exploded corn stalk Enhanced kinetics Neutral solvent extraction Depolymerization characterization
ISSN号1383-5866
英文摘要In this work, the alkaline extraction processes of lignin from untreated and steam-exploded corn stalk were compared and the enhanced extraction process was investigated by neutral solvent extraction and structural analysis of lignin. It was found that a first order model could readily simulate the lignin extraction from untreated stalk while it was helpless to describe the enhanced process after steam explosion due to the intense dissolution of lignin at the beginning stage of extraction. The lignin extracted by neutral solvent from ball-milled corn stalk and its structural characterization demonstrated that the poor description of extraction process by a first order model was mainly attributed to the considerable depolymerization during steam explosion. Due to the depolymerization of lignin, the alkaline extraction after steam explosion became the direct dissolution of depolymerized lignin and was successfully simulated by a second-order model. Finally, the activation energy of lignin alkali-extraction decreased 37.78% after steam explosion treatment with 1.8 MPa and 5 min, which indicated that milder extraction conditions were available to extract lignin from steam-exploded corn stalk. This study also provides a basic guidance for delignification approaches of lignocelluloses after steam explosion. (C) 2015 Elsevier B.V. All rights reserved.
WOS标题词Science & Technology ; Technology
类目[WOS]Engineering, Chemical
研究领域[WOS]Engineering
关键词[WOS]MILLED-WOOD LIGNIN ; DELIGNIFICATION KINETICS ; EXPLOSION ; FRACTIONATION ; SPECTROSCOPY ; CHEMISTRY ; MECHANISM ; BIOFUELS
收录类别SCI
语种英语
WOS记录号WOS:000368868600011
源URL[http://ir.ipe.ac.cn/handle/122111/20589]  
专题过程工程研究所_生化工程国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
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GB/T 7714
Wang, Guanhua,Chen, Hongzhang. Enhanced lignin extraction process from steam exploded corn stalk[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2016,157(JAN):93-101.
APA Wang, Guanhua,&Chen, Hongzhang.(2016).Enhanced lignin extraction process from steam exploded corn stalk.SEPARATION AND PURIFICATION TECHNOLOGY,157(JAN),93-101.
MLA Wang, Guanhua,et al."Enhanced lignin extraction process from steam exploded corn stalk".SEPARATION AND PURIFICATION TECHNOLOGY 157.JAN(2016):93-101.

入库方式: OAI收割

来源:过程工程研究所

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