中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Preparation of rutile titanium dioxide pigment from low-grade titanium slag pretreated by the NaOH molten salt method

文献类型:期刊论文

作者Liu Yahui1,2; Meng Fancheng1,2; Fang Fuqiang1,2; Wang Weijing1,2; Chu Jinglong1,2; Qi Tao1,2
刊名DYES AND PIGMENTS
出版日期2016-02-01
卷号125期号:FEB页码:384-391
关键词Pretreatment of low-grade titanium slag NaOH molten salt method Sulfate process Hydrolysis with impurity Doping of H2TiO3 Rutile TiO2 pigments
ISSN号0143-7208
英文摘要Low-grade titanium slag with a high accumulation of Mg, Al, Si, and the refractory structure of spinel, was sodiumized-oxidized to make it usable in the sulfate process for TiO2 pigment production. In the sodiumized-oxidized process, the Ti3O5 and Mg2SiO4 transform into Na2TiO3 and Na2MgSiO4, respectively. From combined ICP-OES with XRD refinement of the molten NaOH intermediate, the ideal stoichiometric ratio of NaOH to slag was calculated to be 0.9:1. After acidolysis of the intermediate, the obtained TiOSO4 solution, with Mg2+ and Al3+ impurities, was hydrolyzed to prepare metatitanic acid (H2TiO3) with a suitable particle size D(0.5) of 1.0-1.5 pi m. The particle size D(0.5) of the hydrolyzed H2TiO3 decreased, while the concentration of Mg2+ and Al3+ increased. Finally, under optimal doping and calcination conditions, the rutile content of the prepared sample was 97.0%, and the achromic abilities of TCS and SCX were 1937 and 1.54, respectively. (c) 2015 Elsevier Ltd. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Engineering, Chemical ; Materials Science, Textiles
研究领域[WOS]Chemistry ; Engineering ; Materials Science
关键词[WOS]SODIUM-HYDROXIDE ; SULFATE-SOLUTION ; METATITANIC ACID ; WHITE PIGMENT ; HYDROLYSIS ; TIO2 ; TRANSFORMATION ; KINETICS ; DECOMPOSITION ; CALCINATION
收录类别SCI
语种英语
WOS记录号WOS:000367777100048
源URL[http://ir.ipe.ac.cn/handle/122111/20258]  
专题过程工程研究所_湿法冶金清洁生产技术国家工程实验室
作者单位1.Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Liu Yahui,Meng Fancheng,Fang Fuqiang,et al. Preparation of rutile titanium dioxide pigment from low-grade titanium slag pretreated by the NaOH molten salt method[J]. DYES AND PIGMENTS,2016,125(FEB):384-391.
APA Liu Yahui,Meng Fancheng,Fang Fuqiang,Wang Weijing,Chu Jinglong,&Qi Tao.(2016).Preparation of rutile titanium dioxide pigment from low-grade titanium slag pretreated by the NaOH molten salt method.DYES AND PIGMENTS,125(FEB),384-391.
MLA Liu Yahui,et al."Preparation of rutile titanium dioxide pigment from low-grade titanium slag pretreated by the NaOH molten salt method".DYES AND PIGMENTS 125.FEB(2016):384-391.

入库方式: OAI收割

来源:过程工程研究所

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