中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Interface Reactions Between Sealing Glass and Metal Interconnect Under Static and Dynamic Heat Treatment Conditions

文献类型:期刊论文

作者Peng, Lian1; Zhu, Qingshan1; Xie, Zhaohui1; Wang, Ping2
刊名JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY
出版日期2015-12-01
卷号12期号:6页码:1
关键词sealing glass interface reactions thermal cycling aging solid oxide fuel cells
ISSN号1550-624X
通讯作者Zhu, QS (reprint author), Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Zhong Guan Cun,POB 353, Beijing 100190, Peoples R China.
英文摘要Chemical compatibility of sealing glass with metal interconnects is a critical issue for planar solid oxide fuel cell (SOFC). In this paper, interface reactions between a sealing glass and a ferritic metal interconnect (SS410) are tested under three different heat treatment conditions: sealing (static), aging (static), and thermal cycling (dynamic). The results show that the BaCrO4 crystals with two different morphology (round-shaped and needle-shaped) form both at the three-phase boundary (where air, glass, and SS410 meet) and on the surface of the sealing glass under the three conditions. Round-shaped BaCrO4 crystals form with low O-2 concentration and short reaction time. Needle-shaped BaCrO4 crystals form with high O-2 concentration and long reaction time. For the thermal cycling condition, the BaCrO4 formed at early stages causes the delamination of the sealing interface. Then, O-2 diffuses into the interior interface along the delamination path, which results in the formation of BaCrO4 at the interior interface. The delaminationenhanced BaCrO4 formation during thermal cycling will lead to crack along the sealing interface, causing the striking increase of leak rates.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Electrochemistry ; Energy & Fuels
研究领域[WOS]Electrochemistry ; Energy & Fuels
关键词[WOS]OXIDE FUEL-CELLS ; OXYGEN ; STABILITY ; COMPATIBILITY ; DIFFUSION
收录类别SCI
原文出处ASME
语种英语
WOS记录号WOS:000370968300010
源URL[http://ir.ipe.ac.cn/handle/122111/20649]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Zhong Guan Cun,POB 353, Beijing 100190, Peoples R China
2.MEP Minist Environm Protect, Nucl & Radiat Safety Ctr, Beijing 100082, Peoples R China
推荐引用方式
GB/T 7714
Peng, Lian,Zhu, Qingshan,Xie, Zhaohui,et al. Interface Reactions Between Sealing Glass and Metal Interconnect Under Static and Dynamic Heat Treatment Conditions[J]. JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY,2015,12(6):1.
APA Peng, Lian,Zhu, Qingshan,Xie, Zhaohui,&Wang, Ping.(2015).Interface Reactions Between Sealing Glass and Metal Interconnect Under Static and Dynamic Heat Treatment Conditions.JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY,12(6),1.
MLA Peng, Lian,et al."Interface Reactions Between Sealing Glass and Metal Interconnect Under Static and Dynamic Heat Treatment Conditions".JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY 12.6(2015):1.

入库方式: OAI收割

来源:过程工程研究所

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