Gold-catalyzed formation of core-shell gold-palladium nanoparticles with palladium shells up to three atomic layers
文献类型：期刊论文
| 作者 | Chen, Dong1,2; Li, Jiaqi1,2; Cui, Penglei1; Liu, Hui1,3; Yang, Jun1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2016 |
| 卷号 | 4期号:10页码:3813-3821 |
| 关键词 | OXYGEN REDUCTION REACTION FORMIC-ACID OXIDATION ELECTROCATALYTIC ACTIVITY PHASE-TRANSFER FUEL-CELLS TRICHLOROETHENE HYDRODECHLORINATION ELECTRONIC-STRUCTURE ENHANCED ACTIVITY HIGHLY EFFICIENT LATTICE-STRAIN |
| ISSN号 | 2050-7488 |
| 通讯作者 | Yang, J (reprint author), Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China. |
| 英文摘要 | Ultrathin metal layers formed on seed particles with different lattice parameters usually exhibit enhanced catalytic performance for a given chemical reaction due to the sufficient lattice strain effect induced by the core region. Herein, we report a gold-catalyzed strategy for the synthesis of core-shell gold-palladium nanoparticles with subnanometer-thick palladium shells towards oxygen reduction reaction. In this approach, owing to the catalysis of gold particles, the reduction of palladium precursors would only occur on the surface of gold cores, preventing the newly formed palladium atoms from self-nucleation. The deposition of palladium atoms gradually changes the surface property of gold seeds, and in particular, the catalytic reduction of palladium ions ceases when 3 palladium atomic layers are deposited on the gold cores. In comparison with the commercial palladium catalysts, the core-shell gold-palladium nanoparticles with subnanometer-thick palladium shells display superior activity and durability in catalyzing the oxygen reduction reaction, mainly due to the lattice tensile effect in palladium shells induced by the gold cores, which sufficiently balances the bond-breaking and bond-making steps of the oxygen reduction reaction process. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Materials Science |
| 关键词[WOS] | OXYGEN REDUCTION REACTION ; FORMIC-ACID OXIDATION ; ELECTROCATALYTIC ACTIVITY ; PHASE-TRANSFER ; FUEL-CELLS ; TRICHLOROETHENE HYDRODECHLORINATION ; ELECTRONIC-STRUCTURE ; ENHANCED ACTIVITY ; HIGHLY EFFICIENT ; LATTICE-STRAIN |
| 收录类别 | SCI |
| 原文出处 | ROYAL SOC CHEMISTRY |
| 语种 | 英语 |
| WOS记录号 | WOS:000371967000027 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/20653]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, 19AYuquan Rd, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Ctr Mesosci, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Dong,Li, Jiaqi,Cui, Penglei,et al. Gold-catalyzed formation of core-shell gold-palladium nanoparticles with palladium shells up to three atomic layers[J]. JOURNAL OF MATERIALS CHEMISTRY A,2016,4(10):3813-3821. |
| APA | Chen, Dong,Li, Jiaqi,Cui, Penglei,Liu, Hui,&Yang, Jun.(2016).Gold-catalyzed formation of core-shell gold-palladium nanoparticles with palladium shells up to three atomic layers.JOURNAL OF MATERIALS CHEMISTRY A,4(10),3813-3821. |
| MLA | Chen, Dong,et al."Gold-catalyzed formation of core-shell gold-palladium nanoparticles with palladium shells up to three atomic layers".JOURNAL OF MATERIALS CHEMISTRY A 4.10(2016):3813-3821. |
入库方式： OAI收割
来源：过程工程研究所
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