Morphological and Structural Diversity of Molybdenum Oxide-Based Hybrid Materials Prepared through PEG Induction
文献类型：期刊论文
| 作者 | Li, Xiao-yan1,2,3 ; Xiao, Qing-gui1,2; Ning, Peng-ge1,2; Xu, Hong-bin1,2; Zhang, Yi1,2
|
| 刊名 | CRYSTAL GROWTH & DESIGN
 |
| 出版日期 | 2016-03-01 |
| 卷号 | 16期号:3页码:1512-1518 |
| 关键词 | POLYMER-CONTROLLED CRYSTALLIZATION HIGH-PRESSURE PHASE LITHIUM INTERCALATION CRYSTAL STRUCTURE ANODE MATERIAL MOO3 TRIOXIDE DIFFRACTION BATTERIES OXIDATION |
| ISSN号 | 1528-7483 |
| 通讯作者 | Xiao, QG (reprint author), Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydrometallurg Cleaner Prod Technol, Beijing 100190, Peoples R China. |
| 英文摘要 | A facile and shape-controlled crystallization process for preparing molybdenum oxide-based hybrid materials (MOBHMs) from peroxomolybdate solutions was proposed. The morphology of the MOBHMs could be effectively regulated by the assembly of polyethylene glycol (PEG), which acted as a mild reducing agent and a structure-directing agent. The effects of polymer concentration, reaction temperature, and time on the crystal phase and morphology of the MOBHMs were investigated in detail. It was found that the morphologies of amorphous products changed from sphere to a mixture of sphere and cube and then to cube with increased reaction temperature in the presence of 100 g L-1 of PEG. At 70 degrees C, monoclinic H2MoO5 with a ribbon shape was obtained in the absence of PEG. Moreover, increasing the polymer concentration resulted in a morphology transition from ribbon to sphere and then to cube. Correspondingly, phases transition occurred from triclinic MoO3 center dot H2O to amorphous products. Additionally, the phase and morphology of the as-prepared samples hardly changed with prolonged reaction time. A possible combination and growth mechanism has been proposed for the formation of the MOBHMs in aqueous solutions. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 学科主题 | Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary ; Chemistry ; Crystallography ; Materials Science |
| 类目[WOS] | Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Crystallography ; Materials Science |
| 关键词[WOS] | POLYMER-CONTROLLED CRYSTALLIZATION ; HIGH-PRESSURE PHASE ; LITHIUM INTERCALATION ; CRYSTAL STRUCTURE ; ANODE MATERIAL ; MOO3 ; TRIOXIDE ; DIFFRACTION ; BATTERIES ; OXIDATION |
| 收录类别 | SCI |
| 原文出处 | AMER CHEMICAL SOC |
| 语种 | 英语 |
| WOS记录号 | WOS:000371453900047 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/20667]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydrometallurg Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xiao-yan,Xiao, Qing-gui,Ning, Peng-ge,et al. Morphological and Structural Diversity of Molybdenum Oxide-Based Hybrid Materials Prepared through PEG Induction[J]. CRYSTAL GROWTH & DESIGN,2016,16(3):1512-1518. |
| APA | Li, Xiao-yan,Xiao, Qing-gui,Ning, Peng-ge,Xu, Hong-bin,&Zhang, Yi.(2016).Morphological and Structural Diversity of Molybdenum Oxide-Based Hybrid Materials Prepared through PEG Induction.CRYSTAL GROWTH & DESIGN,16(3),1512-1518. |
| MLA | Li, Xiao-yan,et al."Morphological and Structural Diversity of Molybdenum Oxide-Based Hybrid Materials Prepared through PEG Induction".CRYSTAL GROWTH & DESIGN 16.3(2016):1512-1518. |
入库方式： OAI收割
来源：过程工程研究所
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