Supported ultrafine ruthenium oxides with specific capacitance up to 1099 F g(-1) for a supercapacitor
文献类型：期刊论文
| 作者 | Wang, Pengfei1,2; Liu, Hui1,3; Xu, Yuxing1; Chen, Yunfa1 ; Yang, Jun1; Tan, Qiangqiang1
|
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2016-03-10 |
| 卷号 | 194期号:MAR页码:211-218 |
| 关键词 | Ruthenium oxide Supercapacitor Ultrafine Ruthenium nanoclusters Specific capacitance |
| ISSN号 | 0013-4686 |
| 通讯作者 | Yang, J |
| 英文摘要 | Reducing the particle size is a straightforward way to increase the specific surface area of ruthenium oxide, which usually translates to the high specific capacitance for a supercapacitor. Herein, we report a facile strategy to fabricate ultrafine ruthenium oxides supported on various carbon-based substrates (carbon powders, carbon nanotubes, or reduced graphene oxides) as excellent electrode materials for a supercapacitor. The novelty of this work lies in its synthetic approach, which involves an aqueous synthesis of ruthenium nanoclusters under the control of pH value, and an air oxidation-based conversion process. In particular, owing to their ultrafine particle size, the as-prepared carbon-, carbon nanotube-, or reduced graphene oxide-supported ruthenium oxides exhibit specific capacitance as high as 879.1 F g(-1), 966.8 F g(-1) and 1099.6 F g(-1), respectively, for a supercapacitor at a current density of 0.5 A g(-1). The specific capacitance maintains 98.4% (for carbon supports), 98.0% (for carbon nanotube supports) and 98.4% (for reduced graphene oxide supports) at current density of 1 A g(-1) with good cycling stability. The remarkable simplicity and environmental friendliness of this synthesis may provide a liable quantity production route to produce ruthenium oxides as highly efficient electrode materials for a supercapacitor. (C) 2016 Elsevier Ltd. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 学科主题 | Electrochemistry ; Electrochemistry |
| 类目[WOS] | Electrochemistry |
| 研究领域[WOS] | Electrochemistry |
| 关键词[WOS] | EXCELLENT ELECTRODE MATERIALS ; RUO2 NANOPARTICLES ; REDUCTION METHOD ; FACILE SYNTHESIS ; CARBON ; PERFORMANCE ; COMPOSITES ; GRAPHENE ; PARTICLES ; METAL |
| 收录类别 | SCI |
| 原文出处 | PERGAMON-ELSEVIER SCIENCE LTD |
| 语种 | 英语 |
| WOS记录号 | WOS:000372523300024 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/20671]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Ctr Mesosci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Pengfei,Liu, Hui,Xu, Yuxing,et al. Supported ultrafine ruthenium oxides with specific capacitance up to 1099 F g(-1) for a supercapacitor[J]. ELECTROCHIMICA ACTA,2016,194(MAR):211-218. |
| APA | Wang, Pengfei,Liu, Hui,Xu, Yuxing,Chen, Yunfa,Yang, Jun,&Tan, Qiangqiang.(2016).Supported ultrafine ruthenium oxides with specific capacitance up to 1099 F g(-1) for a supercapacitor.ELECTROCHIMICA ACTA,194(MAR),211-218. |
| MLA | Wang, Pengfei,et al."Supported ultrafine ruthenium oxides with specific capacitance up to 1099 F g(-1) for a supercapacitor".ELECTROCHIMICA ACTA 194.MAR(2016):211-218. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。