中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Intramolecular aggregation and optical limiting properties of triazine-linked mono-, bis- and tris-phthalocyanines

文献类型:期刊论文

作者Chen, Jun1,2; Zhang, Tao1; Wang, Shuangqing1; Hu, Rui1; Li, Shayu1; Ma, Jin Shi1; Yang, Guoqiang1
刊名SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
出版日期2015-10-05
卷号149页码:426-433
关键词Phthalocyanine Triazine Optical limiting properties Intramolecular aggregation Photophysical properties
英文摘要A series of triazine-linked mono-, bis- and tris-phthalocyanines are synthesized, intramolecular aggregation is found in bis- and tris-phthalocyanines via pi-pi stacking interaction. Theoretical and experimental studies reveal the formation of the intramolecular aggregation. The spectrographic, photophysical and nonlinear optical properties of these compounds are adjusted for the formation of the intramolecular aggregation. The bis-phthalocyanine dimer presents smaller fluorescence quantum yield, lower triplet formation yield and the triplet-minus-ground state extinction coefficient, which causes poorer optical limiting performance. It is interesting that the tris-phthalocyanine is composed of a mono-phthalocyanine part and a bis-phthalocyanine part, the optical limiting property of the tris-phthalocyanine is similar to that of mono-phthalocyanine. (C) 2015 Elsevier B.V. All rights reserved.
收录类别SCI
语种英语
公开日期2016-05-09
源URL[http://ir.iccas.ac.cn/handle/121111/27694]  
专题化学研究所_光化学实验室
作者单位1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Jiangxi Univ Sci & Technol, Sch Mat Sci & Engn, Ganzhou 341000, Peoples R China
推荐引用方式
GB/T 7714
Chen, Jun,Zhang, Tao,Wang, Shuangqing,et al. Intramolecular aggregation and optical limiting properties of triazine-linked mono-, bis- and tris-phthalocyanines[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2015,149:426-433.
APA Chen, Jun.,Zhang, Tao.,Wang, Shuangqing.,Hu, Rui.,Li, Shayu.,...&Yang, Guoqiang.(2015).Intramolecular aggregation and optical limiting properties of triazine-linked mono-, bis- and tris-phthalocyanines.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,149,426-433.
MLA Chen, Jun,et al."Intramolecular aggregation and optical limiting properties of triazine-linked mono-, bis- and tris-phthalocyanines".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 149(2015):426-433.

入库方式: OAI收割

来源:化学研究所

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