Intramolecular aggregation and optical limiting properties of triazine-linked mono-, bis- and tris-phthalocyanines
文献类型:期刊论文
作者 | Chen, Jun1,2; Zhang, Tao1; Wang, Shuangqing1; Hu, Rui1; Li, Shayu1; Ma, Jin Shi1; Yang, Guoqiang1 |
刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
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出版日期 | 2015-10-05 |
卷号 | 149页码:426-433 |
关键词 | Phthalocyanine Triazine Optical limiting properties Intramolecular aggregation Photophysical properties |
英文摘要 | A series of triazine-linked mono-, bis- and tris-phthalocyanines are synthesized, intramolecular aggregation is found in bis- and tris-phthalocyanines via pi-pi stacking interaction. Theoretical and experimental studies reveal the formation of the intramolecular aggregation. The spectrographic, photophysical and nonlinear optical properties of these compounds are adjusted for the formation of the intramolecular aggregation. The bis-phthalocyanine dimer presents smaller fluorescence quantum yield, lower triplet formation yield and the triplet-minus-ground state extinction coefficient, which causes poorer optical limiting performance. It is interesting that the tris-phthalocyanine is composed of a mono-phthalocyanine part and a bis-phthalocyanine part, the optical limiting property of the tris-phthalocyanine is similar to that of mono-phthalocyanine. (C) 2015 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2016-05-09 |
源URL | [http://ir.iccas.ac.cn/handle/121111/27694] ![]() |
专题 | 化学研究所_光化学实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Jiangxi Univ Sci & Technol, Sch Mat Sci & Engn, Ganzhou 341000, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Jun,Zhang, Tao,Wang, Shuangqing,et al. Intramolecular aggregation and optical limiting properties of triazine-linked mono-, bis- and tris-phthalocyanines[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2015,149:426-433. |
APA | Chen, Jun.,Zhang, Tao.,Wang, Shuangqing.,Hu, Rui.,Li, Shayu.,...&Yang, Guoqiang.(2015).Intramolecular aggregation and optical limiting properties of triazine-linked mono-, bis- and tris-phthalocyanines.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,149,426-433. |
MLA | Chen, Jun,et al."Intramolecular aggregation and optical limiting properties of triazine-linked mono-, bis- and tris-phthalocyanines".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 149(2015):426-433. |
入库方式: OAI收割
来源:化学研究所
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