中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Pressure-induced amorphization of ionic liquid [HMIM][PF6]

文献类型:期刊论文

作者Ren, Yufen1; Li, Haining1; Zhu, Xiang1; Chen, Liucheng1; Su, Lei1,2; Yang, Kun1; Yang, Guoqiang2; Wang, Hua
刊名CHEMICAL PHYSICS LETTERS
出版日期2015-06-01
卷号629页码:8-12
英文摘要Phase behavior of ionic liquid [HMIM][PF6] has been investigated under high pressure up to 5.6 GPa at room temperature. The results indicated that [HMIM][PF6] might experience a phase transition at about 3.4 GPa upon compression, which could be identified as solidification to superpressurized glass by ruby R-1 line broadening measurement and synchrotron X-ray diffraction (XRD) patterns. For conformational equilibrium, the fraction of all-anti (AAAA) conformer increased upon compression, while the conformational change was independent of temperature. These facts indicated that there were large differences of the structure in response to the extreme conditions, especially in the structure of the cation. (C) 2015 Elsevier B.V. All rights reserved.
收录类别SCI
语种英语
公开日期2016-05-09
源URL[http://ir.iccas.ac.cn/handle/121111/28122]  
专题化学研究所_光化学实验室
作者单位1.Zhengzhou Univ Light Ind, High Pressure Res Ctr Sci & Technol, Zhengzhou 450002, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
推荐引用方式
GB/T 7714
Ren, Yufen,Li, Haining,Zhu, Xiang,et al. Pressure-induced amorphization of ionic liquid [HMIM][PF6][J]. CHEMICAL PHYSICS LETTERS,2015,629:8-12.
APA Ren, Yufen.,Li, Haining.,Zhu, Xiang.,Chen, Liucheng.,Su, Lei.,...&Wang, Hua.(2015).Pressure-induced amorphization of ionic liquid [HMIM][PF6].CHEMICAL PHYSICS LETTERS,629,8-12.
MLA Ren, Yufen,et al."Pressure-induced amorphization of ionic liquid [HMIM][PF6]".CHEMICAL PHYSICS LETTERS 629(2015):8-12.

入库方式: OAI收割

来源:化学研究所

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