Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion
文献类型：期刊论文
| 作者 | Liu, Qing-yu1; Hu, Lian-rui2; Chen, Hui2; He, Sheng-gui1 |
| 刊名 | CHINESE JOURNAL OF CHEMICAL PHYSICS
 |
| 出版日期 | 2015-08-01 |
| 卷号 | 28期号:4页码:452-458 |
| 关键词 | Diatomic molecules Electronic structure Spin-orbit splitting Photoelectron imaging spectroscopy ab initio calculations |
| 英文摘要 | The diatomic ZrO- anion has been prepared by laser ablation and studied by photoelectron imaging spectroscopy combined with quantum chemistry calculations. The observed photoelectron spectra can be well assigned on the basis of reported optical spectroscopy and high-level ab initio calculations. The ground state of ZrO- is a 2,6, state with spin-orbit splitting of 578 +/- 12 cm(-1). The electron affinity of ZrO is 1.249 +/- 0.005 eV. For the first time, the c(3)Sigma(-) state of ZrO has been experimentally observed at 13316 +/- 24 cm(-1) with respect to the X-1 Sigma(+) ground state. A comparison between ZrO and the isoelectronic molecule NbN has been made. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28377]  |
| 专题 | 化学研究所_光化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Photochem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Qing-yu,Hu, Lian-rui,Chen, Hui,et al. Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2015,28(4):452-458. |
| APA | Liu, Qing-yu,Hu, Lian-rui,Chen, Hui,&He, Sheng-gui.(2015).Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion.CHINESE JOURNAL OF CHEMICAL PHYSICS,28(4),452-458. |
| MLA | Liu, Qing-yu,et al."Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion".CHINESE JOURNAL OF CHEMICAL PHYSICS 28.4(2015):452-458. |
入库方式： OAI收割
来源：化学研究所
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