中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A polymorphic lanthanide complex as selective Co2+ sensor and luminescent timer

文献类型:期刊论文

作者Zeng, Cheng-Hui1,2,3; Meng, Xiao-Ting1,2; Xu, Song-Song1,2; Han, Li-Jun4; Zhong, Shengliang1,2; Jia, Mei-Ye3
刊名SENSORS AND ACTUATORS B-CHEMICAL
出版日期2015-12-31
卷号221页码:127-135
关键词Polymorphic Lanthanide complex Co2+ sensor Luminescent timer
英文摘要A rarely reported polymorphic lanthanide complex is prepared by acetylacetone (acac) tuning method. Luminescence properties of 1 are studied. Interestingly, 1 is proved to be a multifunctional material. It is a highly selective and sensitive Co2+ sensor, among 24 species, only Co2+ quenching the Tb3+ centered luminescence. The possible sensing mechanism is the decomposition of 1 which induced by Co2+. The limit of detection (LOD) for sensing Co2+ is as low as 330 nM, which is lower than the standard of Chinese environmental protection department. Mechanism study confirmed the luminescence quenching can be ascribed to the decomposition of 1 which induced by Co2+. Further investigations find 1-Co2+ can be applied as tunable luminescent timer, by tuning the ratio of 1/Co2+. CIE coordinates of 1-Co2+ change regularly (has excellent linearity) from green to violet with the time increasing. (C) 2015 Elsevier B.V. All rights reserved.
收录类别SCI
语种英语
公开日期2016-05-09
源URL[http://ir.iccas.ac.cn/handle/121111/28919]  
专题化学研究所_光化学实验室
作者单位1.Jiangxi Normal Univ, Coll Chem & Chem Engn, Key Lab Funct Small Organ Mol, Minist Educ, Nanchang 330022, Peoples R China
2.Jiangxi Normal Univ, Coll Chem & Chem Engn, Jiangxis Key Lab Green Chem, Nanchang 330022, Peoples R China
3.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100864, Peoples R China
4.Huaihai Inst Technol, Sch Math & Sci, Lianyungang 222005, Peoples R China
推荐引用方式
GB/T 7714
Zeng, Cheng-Hui,Meng, Xiao-Ting,Xu, Song-Song,et al. A polymorphic lanthanide complex as selective Co2+ sensor and luminescent timer[J]. SENSORS AND ACTUATORS B-CHEMICAL,2015,221:127-135.
APA Zeng, Cheng-Hui,Meng, Xiao-Ting,Xu, Song-Song,Han, Li-Jun,Zhong, Shengliang,&Jia, Mei-Ye.(2015).A polymorphic lanthanide complex as selective Co2+ sensor and luminescent timer.SENSORS AND ACTUATORS B-CHEMICAL,221,127-135.
MLA Zeng, Cheng-Hui,et al."A polymorphic lanthanide complex as selective Co2+ sensor and luminescent timer".SENSORS AND ACTUATORS B-CHEMICAL 221(2015):127-135.

入库方式: OAI收割

来源:化学研究所

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