Successive Cu/Pd transmetalation relay catalysis in stereoselective synthesis of tetraarylethenes
文献类型：期刊论文
| 作者 | Song, Chuanling1; Sun, Yihua2; Wang, Jianwu1; Chen, Hui2; Yao, Jiannian2; Tung, Chen-Ho1; Xu, Zhenghu1,3 |
| 刊名 | Organic Chemistry Frontiers
 |
| 出版日期 | 2015 |
| 卷号 | 2期号:10页码:1366-1373 |
| 英文摘要 | A new and efficient strategy for the synthesis of tetraaryl-substituted olefins has been developed. With a Cu/Pd-catalyzed isomerization/insertion/oxidative coupling cascade reaction of cyclopropene with internal alkynes, a wide variety of cis-tetrasubstituted olefins were synthesized in good yields as single stereoisomers. The photophysical properties of these novel tetraarylethenes were fully characterized and proved to be good AIE (aggregation-induced emission) luminogens. Experimental studies and theoretical calculation indicated that Cu(I) and Pd(II) were the actual catalysts. A novel deprotonative Cu-catalyzed cyclopropene cycloisomerization and subsequent successive Cu/Pd transmetalation relay mechanism was proposed for the discovered reaction. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29221]  |
| 专题 | 化学研究所_光化学实验室 |
| 作者单位 | 1.Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Shandong, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Chuanling,Sun, Yihua,Wang, Jianwu,et al. Successive Cu/Pd transmetalation relay catalysis in stereoselective synthesis of tetraarylethenes[J]. Organic Chemistry Frontiers,2015,2(10):1366-1373. |
| APA | Song, Chuanling.,Sun, Yihua.,Wang, Jianwu.,Chen, Hui.,Yao, Jiannian.,...&Xu, Zhenghu.(2015).Successive Cu/Pd transmetalation relay catalysis in stereoselective synthesis of tetraarylethenes.Organic Chemistry Frontiers,2(10),1366-1373. |
| MLA | Song, Chuanling,et al."Successive Cu/Pd transmetalation relay catalysis in stereoselective synthesis of tetraarylethenes".Organic Chemistry Frontiers 2.10(2015):1366-1373. |
入库方式： OAI收割
来源：化学研究所
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