Cavity-confined acceleration of iron cycle for the Fenton-like reaction by beta-CD-benzoquinone host-guest complex under visible irradiation
文献类型：期刊论文
| 作者 | Fu, Liting1; Zhao, Zhenwen2; Ma, Jiahai1; Hu, Xuefeng3 |
| 刊名 | CATALYSIS COMMUNICATIONS
 |
| 出版日期 | 2015-05-02 |
| 卷号 | 65页码:96-101 |
| 关键词 | Host-guest complex Iron cycle Visible irradiation Fenton |
| 英文摘要 | The catalyst (CDBQ) that was prepared from beta-cydodextrin (beta-CD) and 2,5-dihydroxy-1,4-benzoquinone (2,5-DBQ) achieved the cavity-confined acceleration of iron cycle under visible irradiation. The semi-quinone-like (SQ) radical was generated from photoexcitation of 2,5-DBQ within the beta-CD's cavity. The SQ radical as an electron donor could coordinate with iron ions, and thus 2,5-DBQ shuttled one electron between Fe3+ and Fe2+ via Fe-dihydroxybenzoquinone complex process. In Fenton reactions, CDBQ greatly increased the HO center dot yield, and thus significantly accelerated the degradation of dyes. The cavity-confined acceleration of iron cycle has promising applications in photo-Fenton system for the efficient decontamination for wastewater. (C) 2015 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28544]  |
| 专题 | 化学研究所_活体分析化学实验室 |
| 作者单位 | 1.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Mass Spectrum Ctr, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, Liting,Zhao, Zhenwen,Ma, Jiahai,et al. Cavity-confined acceleration of iron cycle for the Fenton-like reaction by beta-CD-benzoquinone host-guest complex under visible irradiation[J]. CATALYSIS COMMUNICATIONS,2015,65:96-101. |
| APA | Fu, Liting,Zhao, Zhenwen,Ma, Jiahai,&Hu, Xuefeng.(2015).Cavity-confined acceleration of iron cycle for the Fenton-like reaction by beta-CD-benzoquinone host-guest complex under visible irradiation.CATALYSIS COMMUNICATIONS,65,96-101. |
| MLA | Fu, Liting,et al."Cavity-confined acceleration of iron cycle for the Fenton-like reaction by beta-CD-benzoquinone host-guest complex under visible irradiation".CATALYSIS COMMUNICATIONS 65(2015):96-101. |
入库方式： OAI收割
来源：化学研究所
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